Synthesis of rhenium chelated MAG3 functionalized rosette nanotubes

Alsbaiee, Alaaeddin; Jules, Mustapha St.; Beingessner, Rachel L.; Cho, Jae-Young; Yamazaki, Takeshi; Fenniri, Hicham

doi:10.1016/j.tetlet.2012.01.090

Cited by 7 publications

(1 citation statement)

References 41 publications

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“…Detailed microscopy and spectroscopy studies have shown that these architectures have an exceptionally controlled organization that is based on these cumulatively strong and directional noncovalent interactions . As well, these materials have excellent chemical and physical tuning capabilities, owing to their ease of surface functionalization with bioactive molecules, inorganic complexes, nanoparticles, and other organic moieties. By extending the length of the G∧C scaffold, − the RNT channel diameter can also be increased from 1.1 nm (bicyclic motif) to 1.4 nm (tricyclic motif) , or 1.7 nm (tetracyclic motif) .…”

Section: Introductionmentioning

confidence: 99%

Covalent Capture of Self-Assembled Rosette Nanotubes

et al. 2012

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Rosette nanotubes (RNTs) are self-assembled tubular architectures which have extensive chemical and physical tuning capabilities, owing to their ease of surface functionalization and flexible inner channel design. To marry these tunable features of the RNTs with the enhanced stability of a covalent polymer, here we demonstrate the covalent capture of the RNT supramolecular structure by polymerizing alkyldiamine functional groups expressed on their outer periphery in the presence of adipoyl chloride (nylon-6,6 process). The resulting polymeric materials were characterized using proton nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy, dynamic light scattering, and differential scanning calorimetry. Transmission and scanning electron microscopy revealed the formation of fibers and films composed of RNTs.

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Section: Introductionmentioning

confidence: 99%

Covalent Capture of Self-Assembled Rosette Nanotubes

et al. 2012

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Bioactive Rosette Nanotubes for Bone Tissue Engineering and Drug Delivery

et al. 2013

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Supramolecular Amphiphiles Based on Multiple Hydrogen Bonds

Kimizuka¹

2017

Supramolecular Amphiphiles

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The molecular design principles, characteristics and development of supramolecular amphiphiles are summarized. Supramolecular amphiphiles are designed by using multiple hydrogen bonding as an essential source of noncovalent interactions in aqueous self-assembly. The supramolecular amphiphiles considered here are composed of molecular pairs designed to acquire enhanced amphiphilicity, i.e., the ability to form stable and ordered molecular assemblies on the formation of multiple—and when more appropriate complementary—hydrogen bonds. These hydrogen bonding mediated amphiphiles further hierarchically self-assemble in a given environment. Their secondary and higher assembly architectures are greatly influenced by the dispersed media via solvophilic–solvophobic interactions.

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Synthesis of rhenium chelated MAG3 functionalized rosette nanotubes

Cited by 7 publications

References 41 publications

Covalent Capture of Self-Assembled Rosette Nanotubes

Covalent Capture of Self-Assembled Rosette Nanotubes

Bioactive Rosette Nanotubes for Bone Tissue Engineering and Drug Delivery

Supramolecular Amphiphiles Based on Multiple Hydrogen Bonds

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