Synthesis of reactive dyes by the introduction of Phenyl Urea derivatives into the triazine ring and their application on different fibers

Patel, Manoj J.; Tandel, R. C.

doi:10.1016/j.matpr.2021.03.575

Cited by 4 publications

(4 citation statements)

References 6 publications

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“…Urea derivatives are prevalent organic compounds with a variety of applications such as resin precursors, dyes, agrochemicals, , and pharmaceutical drugs , and in supramolecular chemistry . Additionally, polyureas are useful classes of plastics with a range of applications for construction materials (e.g., coatings, adhesives) and biomedical industry (e.g., drug delivery) and have a current annual market of USD 885 million .…”

Section: Introductionmentioning

confidence: 99%

Manganese-Catalyzed Dehydrogenative Synthesis of Urea Derivatives and Polyureas

et al. 2022

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Urea derivatives have significant applications in the synthesis of resin precursors, dyes, agrochemicals, and pharmaceutical drugs. Furthermore, polyureas are useful plastics with applications in coating, adhesive, and biomedical industries. However, the conventional methods for the synthesis of urea derivatives and polyureas involve toxic reagents such as (di)isocyanates, phosgene, CO, and azides. We present here the synthesis of (poly)ureas using much less toxic reagents(di)amines and methanolvia a catalytic dehydrogenative coupling process. The reaction is catalyzed by a pincer complex of an earthabundant metal, manganese, and liberates H 2 gas, valuable by itself, as the only byproduct, making the overall process highly atomeconomic. A broad variety of symmetrical and unsymmetrical urea derivatives and polyureas have been synthesized in moderate to quantitative yields using this catalytic protocol. Mechanistic insights have also been provided using experiments and DFT computation, suggesting that the reaction proceeds via an isocyanate intermediate.

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Section: Introductionmentioning

confidence: 99%

Manganese-Catalyzed Dehydrogenative Synthesis of Urea Derivatives and Polyureas

et al. 2022

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“…Bi Functional Reactive dyes Z1-Z10 has been reported earlier [14]. The absorbance value of dyes was observed wavelength of maximum absorption (⅄ max ) was 498 nm to 502 nm.…”

Section: Synthesis Of Dyes (Z1 To Z10)mentioning

confidence: 90%

“…Bifunctional reactive dyes Dye Z1-10 has been reported earlier [14]. All synthesized dyes were used for a different type of application on cotton fabrics.…”

Section: Reactive Dye Synthesismentioning

confidence: 99%

Application of Reactive dyes by Dyeing and Printing Method on Cotton Fabric and Study of Antibacterial Activity

Patel

Tandel

2022

Egypt. J. Chem.

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The present work was designed to study bifunctional reactive dyes by printing and cold pad batch method also evaluated their antibacterial activity. The main object of this research paper is to highlight synthesized dyes having excellent fixation abilities for the dyeing and printing industries to further invest upon. All dyes were reported earlier, In the synthesis of reactive dyes phenyl urea derivatives introduced in triazine ring, the dyes have excellent solubility. Synthesized dyes Z1-10 were applied on cotton fabric with cold pad batch dyeing and printing method. The fixation value of dyes in the CPB method and percentage of absorbance in the printing method of dyes were evaluated. Ten synthesized reactive dyes had a 64 % absorbance value in the print method due to the solubility behavior of dyes. The colorimetric data of dyed and printed fabric were examined in the CIELab system. The Fastness properties of dyed and printed fabrics were evaluated through standard test method. Antibacterial activity of synthesized dyes was investigated against different kinds of bacteria on dyed fabric. The synthesized dyes had good Antibacterial affinity compared with selected antibiotics as a reference standard.

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“…The transfer of energy from departed dye molecules to fibre also boosted the stability of reactive dye. Because vinyl sulphone is acid stable and CT (Choloro triazine) is alkali stable, it has strong wet fastness properties.The solubility of synthesized dyes was good gives high fastness properties of dyes.Whashing fastness was depends on fixation of reactive dyes sythesized dyes have good fixation value, so problem of waste water is minimum (Karacakaya et al, 2009;Habibah et al, 2017;Patel et al, 2021;.…”

Section: Fastness Propertiesmentioning

confidence: 99%

Monoazo reactive dyes: Synthesis and application on cotton, silk and wool fibers

Patel,

Sonera,

Bairwa

et al. 2023

Braz. J. of Sci.

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Mono azo reactive dyes are mostly used in textiles industries. The current study was developed to synthesize and apply mono azo reactive dyes. The primary goal of this research article is to highlight synthesized dyes with outstanding fixing properties for the dyeing and printing sectors to invent in future. Diazotized o-anisidine was coupled with several 4-amino-4ʼ-hydroxy benzilidene acetophenone cyanurated coupling component including H-acid, Gamma acid, J-acid, N-methyl J-acid, N-phenyl J-acid, K- acid and peri acid, to create a variety of monoazo reactive dyes. IR and elemental analyses were used to describe them. Moreover, the dyeing capabilities of each of these dyes on silk, wool, and cotton have been evaluated. The wet fastness properties also evaluated. Synthesized mono azo reactive dyes have excellent fixation values as well as fastness properties.

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Synthesis of reactive dyes by the introduction of Phenyl Urea derivatives into the triazine ring and their application on different fibers

Cited by 4 publications

References 6 publications

Manganese-Catalyzed Dehydrogenative Synthesis of Urea Derivatives and Polyureas

Manganese-Catalyzed Dehydrogenative Synthesis of Urea Derivatives and Polyureas

Application of Reactive dyes by Dyeing and Printing Method on Cotton Fabric and Study of Antibacterial Activity

Monoazo reactive dyes: Synthesis and application on cotton, silk and wool fibers

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