Synthesis of PVA Nanofibers to Enhance the Mechanical and Thermal Properties of PMMA Matrix for Denture Base Applications

Abstract

This study attempts to prepare PMMA nano-composite samples armed with polyvinyl alcohol electrospun nanofibers. One layer, two layers, and three layers of nanofiber reinforcement were all utilized. As well as, one drop (0.01 g) and three drops of the cardamom oil were used. Using a differential calorimeter, thermal experiments were carried out, including those for the Tg and the thermal dissociation point. Mechanical tests were conducted on the samples, including compression testing to determine the elongation characteristics, compressive strength, Young's modulus, yield strength, and toughness. All samples were also subjected to an impact strength test. Results showed that the Tg point increased due to the presence of nanofibers from 136 to 195 Celsius, and that 277 Celsius was the thermal breakdown point. According to the mechanical property data, the impact strength increased as the percentage of nanofibers rose and increased further when one drop of cardamom oil was mixed with a very tiny amount (0.01 g) of material. Additionally, it was noted that the samples did not break easily since nanofibers and a drop of cardamom oil were present. Additionally, it was demonstrated that the sample's strength increased to 195 kJ/m2, as well as 0.02 weight % of fibers, the maximum strength value.