Synthesis of Poly(δ-caprolactone) via Bis(phenolate) Rare-Earth Metal Complexes Mediated Ring-Opening Polymerization and Its Chemical Recycling
Hao Jiang,
Zhiyuan Li,
Yanan Dai
et al.
Abstract:New amine-amino-bis(phenolate) ligands (H 2 L tBu and H 2 L Cl ) with a cyclic tertiary amine (pyrrolidine) as a side arm and t Bu or Cl group on the phenolate ring have been prepared. The alkane elimination reaction between these free ligands and rareearth tris(alkyl)s Ln(CH 2 SiMe 3 ) 3 (THF) 2 afforded the corresponding silylalkyl complexes L tBu LnCH 2 SiMe 3 (THF) (Ln = Y (1), Lu (2)) and L Cl YCH 2 SiMe 3 (THF) (3), where the solid-state structure of complex 1 was unambiguously confirmed by X-ray diffrac… Show more
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