“…This and other early Houdry-Air Products patents 15−21 do not show dramatic or very impressive catalyst performance, with claimed DABCO weight yields from total feed ranging from about 8% to near 40%, a significant improvement over prior art. For example, in 1942 O. Hromatka 22,23 reported DABCO yields of around 2−3% and in the mid-1950s J. Ishigura and co-workers report "acceptable yields", 24,25 which considering the state of the art at that time was believed to be somewhere less than the 8−10% range. 13 More recent work by M. Selvaraj et al 26 claim DABCO yields in the high 80% range over mesoporous solid acids (MCM-41 derivatives) from ethanolamine and similars, while J. Armour et al 27,28 claim combined DABCO plus piperazine yields of 81− 89% from ethylenediamine over surface modified pentasil style zeolites.…”
Here we report on the discovery and
development of a new catalyst
based on strontium hydrogen phosphate for efficient production of
DABCO, 1,4-diazabicyclo [2,2,2] octane. It was brought from initial
lab scale discovery to commercial use in less than 1 year. It provides
significant value for production of DABCO via much higher selectivity
and nearly double the productivity of the silica–alumina material
used as the previous commercial catalyst. The value is not only in
higher observed productivity but also in large savings in feedstock
costs derived from the improved reaction selectivity and also a much
longer effective useful lifetime than the previous silica–alumina.
“…This and other early Houdry-Air Products patents 15−21 do not show dramatic or very impressive catalyst performance, with claimed DABCO weight yields from total feed ranging from about 8% to near 40%, a significant improvement over prior art. For example, in 1942 O. Hromatka 22,23 reported DABCO yields of around 2−3% and in the mid-1950s J. Ishigura and co-workers report "acceptable yields", 24,25 which considering the state of the art at that time was believed to be somewhere less than the 8−10% range. 13 More recent work by M. Selvaraj et al 26 claim DABCO yields in the high 80% range over mesoporous solid acids (MCM-41 derivatives) from ethanolamine and similars, while J. Armour et al 27,28 claim combined DABCO plus piperazine yields of 81− 89% from ethylenediamine over surface modified pentasil style zeolites.…”
Here we report on the discovery and
development of a new catalyst
based on strontium hydrogen phosphate for efficient production of
DABCO, 1,4-diazabicyclo [2,2,2] octane. It was brought from initial
lab scale discovery to commercial use in less than 1 year. It provides
significant value for production of DABCO via much higher selectivity
and nearly double the productivity of the silica–alumina material
used as the previous commercial catalyst. The value is not only in
higher observed productivity but also in large savings in feedstock
costs derived from the improved reaction selectivity and also a much
longer effective useful lifetime than the previous silica–alumina.
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