Synthesis of Phenolic Resin-Based Epoxy Resins Containing Acetal Linkages and Degradability of Their Cured Epoxy Resins

Kakichi, Yoshinori; Hashimoto, Tamotsu; Yamaguchi, Ayaka; Urushisaki, Michio; Sakaguchi, Toshikazu; Kawabe, Kentaro; Kondo, Keiichi; Iyo, Hirohumi

doi:10.1295/koron.2015-0063

Cited by 5 publications

(1 citation statement)

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“…Therefore, when preparing microcapsules, it is usually selected as the wall material [31][32][33]. Epoxy resin materials have the high chemical resistance, good adhesion, curing performance, impact resistance, and meet the requirements of environmental protection [34][35][36]. Using the mixture of melamine-formaldehyde resin and rice hull powder as the wall material of microcapsules can have the nice interfacial compatibility with water-based coating.…”

Section: Introductionmentioning

confidence: 99%

Preparation of Melamine-Formaldehyde Resin/Rice Husk Powder Coated Epoxy Resin Microcapsules and Effects of Different Microcapsule Contents on the Properties of Waterborne Coatings on Tilia europaea Surface

Huang

Yan

2022

Coatings

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With the development of economy and science and technology, people put forward higher standards for the performance of the surface coating of wood products, which requires us to carry out innovative research on the coating. In this work, a kind of microcapsule was prepared with melamine-formaldehyde resin/rice husk powder as wall material and epoxy resin as core material. The microcapsules were added to the waterborne acrylic resin coating according to the contents of 0%, 1.0%, 4.0%, 7.0%, 10.0%, 13.0%, 16.0% and 20.0% respectively, and were coated on the surface of the Tilia europaea boards in the form of topcoat. The effects of different contents of microcapsules on the optical properties, mechanical properties and aging resistance of the coating were explored, and the optimal content that can effectively improve the properties of the coating was analyzed. Test results indicated that when the microcapsule content is 7.0%, the comprehensive properties of the coating is optimal. At this time, the color difference of the coating is 6.96, the gloss at 60° is 13.4%, the hardness is 2H, the adhesion grade is 1, and the impact resistance is 12.0 kg·cm. After the aging test, the gloss loss rate decreases, the color difference is 5.69, and the gloss at 60° is 11.6%. The results of aging test show that the coating with epoxy microcapsules has a certain self-healing function. In this study, the microcapsules which can optimize the mechanical properties waterborne coating and prolong the service life of wood were prepared. This can meet the diverse needs of consumers, supply a theoretical reference for the preparation of functional microcapsules, and provide reference value for the functional research of the coating on wood furniture surface.

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