Synthesis of optically active 1,2,5-trimethyl-4-ethynyl-4-piperidols and the corresponding diacetylenic glycols

Abdulganeeva, S. A.; Grishina, G. V.; Potapov, V. M.; Erzhanov, K. B.; Shapovalov, A. A.

doi:10.1007/bf00516210

Cited by 1 publication

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“…A prospective solution to the hunger problem may be offered through compounds that have the ability to increase crop yield, for example by making crops more drought resistant. It is well known that the use of piperidine-containing diacetylene glycols may increase the growth of plants multifold [1][2][3][4][5]. In addition, plants which were processed by piperidine-containing diacetylene glycols prove to be more resistant to drought, temperature changes and diseases [1][2][3][4][5].…”

Section: Fig 1 -Piperidine-containing Diacetylene Glycolsmentioning

confidence: 99%

“…It is well known that the use of piperidine-containing diacetylene glycols may increase the growth of plants multifold [1][2][3][4][5]. In addition, plants which were processed by piperidine-containing diacetylene glycols prove to be more resistant to drought, temperature changes and diseases [1][2][3][4][5]. Treatment by piperidine-containing diacetylene glycols can rapidly increase the annual harvest, especially in hot and arid regions.…”

Section: Fig 1 -Piperidine-containing Diacetylene Glycolsmentioning

confidence: 99%

“…Piperidine-containing compounds have shown great promise as plant growth stimulators [1][2][3][4][5] ( Figure 1). Nowadays in the world one out of eight people does not get enough food.…”

Section: Introductionmentioning

confidence: 99%

“…Dimerization of acetylenic glycols is provided by oxidation in the presence of cuprous (I) chloride (Cu 2 Cl 2 ) and pyridine. 1,2,5 In the present work a new type of compounds with potentially similar positive effects on crop yield and drought resistance was synthesized and studied both experimentally and theoretically. Piperidine-based acetylene glycols were synthesized under the Favorskii reaction.…”

Section: Introductionmentioning

confidence: 99%

“…Piperidine-containing compounds have shown great promise as plant growth stimulators [1][2][3][4][5] (Fig 1).…”

Section: Introductionmentioning

confidence: 99%

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Experimental and density functional theory studies of the novel piperidine-containing acetylene glycols

Mirsakiyeva¹,

Botkina²,

Elgammal³

et al. 2016

Arkivoc

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Synthesis routes of novel piperidine-containing acetylenes are presented. The new molecules are expected to exhibit plant growth stimulation properties. In particular, the yield in a situation of drought is expected to increase. Our synthesis makes use of the Favorskii reaction between cyclohexanone/piperidone and triple-bond containing alcohols. The structures of the obtained molecules were determined using nuclear magnetic resonance (NMR). The electronic structure and geometries of the molecules were studied theoretically using first-principles calculations based on density functional theory. The calculated geometries agree very well with the experimentally determined ones, and also allow us to determine bond lengths, angles and charge distributions inside the molecules.

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Section: Fig 1 -Piperidine-containing Diacetylene Glycolsmentioning

confidence: 99%

Section: Fig 1 -Piperidine-containing Diacetylene Glycolsmentioning

confidence: 99%

“…Piperidine-containing compounds have shown great promise as plant growth stimulators [1][2][3][4][5] ( Figure 1). Nowadays in the world one out of eight people does not get enough food.…”

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

“…Piperidine-containing compounds have shown great promise as plant growth stimulators [1][2][3][4][5] (Fig 1).…”

Section: Introductionmentioning

confidence: 99%

See 3 more Smart Citations

Experimental and density functional theory studies of the novel piperidine-containing acetylene glycols

Mirsakiyeva¹,

Botkina²,

Elgammal³

et al. 2016

Arkivoc

View full text Add to dashboard Cite

show abstract

Synthesis of optically active 1,2,5-trimethyl-4-ethynyl-4-piperidols and the corresponding diacetylenic glycols

Cited by 1 publication

References 0 publications

Experimental and density functional theory studies of the novel piperidine-containing acetylene glycols

Experimental and density functional theory studies of the novel piperidine-containing acetylene glycols

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