Synthesis of Nitrobenzazoles

Kinetic Studies on Nucleophilic Addition Reactions of 4‐X‐substituted Anilines to N1‐methyl‐4‐nitro‐2,1,3 benzothiadiazolium terafluoroborate in Acetonitrile: Reaction Mechanism and Mayr's Approach

“…Compound 3 was prepared according to literature procedures . The N‐methylation of 4‐nitro‐2,1,3‐benzothiadiazole 3 was carried out in a sealed tube.…”

1H, 13C and 15N NMR spectroscopy and tautomerism of nitrobenzotriazoles

“…Nitro derivatives of benzotriazoles have found wide applications in various branches of medicine, technology, and chemistry as ionic liquids, synthones for nanocompounds, and intermediates for organic synthesis. [2,7,8] Prototropic transformations of almost all benzazoles in solutions proceed so quickly on the NMR time scale that varying the solution temperatures does not cause changes in the spectra. [9 -14] In all cases the time-averaged signals are observed in the spectra.…”

An Update on the Synthesis of Benzoxazoles

“…Some 2-(N-Aryl-carboxamidomethylthio)benzoxazoles (16) and corresponding sulfones (17) were prepared, and their antimicrobial activity was assayed against some bacteria and fungi and was found to exhibit 20-70% inhibition at a concentration of 0.1 mg/ml [6].…”

“…Different substituted benzoxazoles (51) are synthesized [16] by distillation of aminocresol hydrochlorides with sodium formate.…”