Synthesis of naphthalene-substituted aromatic esters <i>via</i> Rh(<scp>iii</scp>)-catalyzed C–H bond naphthylation and cascade directing group transformation

Cui, Yue; Li, Siyu; Wang, Hesheng; Zeng, Jing; Wang, Yichen; Bu, Xiubin; Yang, Xiaobo; Zhang, Zhao

doi:10.1039/d2cc05484a

Cited by 2 publications

(1 citation statement)

References 57 publications

(29 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In that work, oxa bicyclic alkenes 226 were used as naphthyl-donor precursors and several aromatic naphthalene substituted esters 227 were produced via a cascade CÀ H naphthylation and directing group transformation, where the imidate moiety was altered into ester (Scheme 57). [91] Scheme 54. Synthesis of diaryl amides via 1,4-aryl shift of imidates.…”

Section: Miscellaneous Applications Of Imidatesmentioning

confidence: 99%

Synthetic Routes to Imidates and Their Applications in Organic Transformation: Recent Progress

Chaidali,

Lykakis

2023

Eur J Org Chem

View full text Add to dashboard Cite

Recent synthetic approaches and diverse applications of imidates are presented in this review. These motifs are successfully used as intermediates in organic transformations, such as the synthesis of N‐heterocycles, natural products and metal complexes with a potential catalytic effect. Consequently, many attempts have been made for the development of efficient and facile synthetic methods of imidates in the past few years, as a continuum of previous paths. A wide range of organic compounds can be used as starting materials for these syntheses, including nitriles, isocyanides, amides etc. which through simple and flexible processes are converted to the desired imidates. Herein, an exploration of the recent synthetic routes of imidates and their diverse applications in organic transformations has been categorized and summarized.

show abstract

Section: Miscellaneous Applications Of Imidatesmentioning

confidence: 99%

Synthetic Routes to Imidates and Their Applications in Organic Transformation: Recent Progress

Chaidali,

Lykakis

2023

Eur J Org Chem

View full text Add to dashboard Cite

show abstract

Synthesis of 3,4,5-trisubstituted phenols via Rh(iii)-catalyzed alkenyl C–H activation assisted by phosphonium cations

Mao

Chen

et al. 2023

Chem. Commun.

View full text Add to dashboard Cite

show abstract

Synthesis of naphthalene-substituted aromatic esters via Rh(iii)-catalyzed C–H bond naphthylation and cascade directing group transformation

Abstract: A regioselective Rh(III)-catalyzed C-H bond naphthylation and cascade directing group (DG) transformation has been realized with aryl imidates and oxa bicyclic alkenes. Diverse naphthalene-substituted aromatic esters were synthesized fruitfully. The...

Cited by 2 publications

References 57 publications

Synthetic Routes to Imidates and Their Applications in Organic Transformation: Recent Progress

Synthetic Routes to Imidates and Their Applications in Organic Transformation: Recent Progress

Synthesis of 3,4,5-trisubstituted phenols via Rh(iii)-catalyzed alkenyl C–H activation assisted by phosphonium cations

Contact Info

Product

Resources

About