Synthesis of nanospherical Fe3BO6 anode material for lithium-ion battery by the rheological phase reaction method

Magnetic and dielectric properties of Fe3BO6 nanoplates prepared through self-combustion method

“…[1][2][3][4][5][6][7][8] This is required for applications of information storage, spintronics, magnets, and power sources for electric and hybrid vehicles.…”

“…A nanoscale borate is rarely prepared so far except Fe 3 BO 5 nanorods are made recently using a hydrothermal method, 17 or a solution phase reaction, 8 and spherical Fe 3 BO 6 nanoparticles made from a rheological phase reaction. 6 Quite good numbers of studies are carried in authors' laboratory on the iron borate glasses with varieties of additives that yield small fibrils of ferrites and iron borates with tailored magnetic as well as dielectric properties. [18][19][20][21][22] In view to this, a new facile synthesis method is developed to obtain a single phase Fe 3 BO 6 crystallites in the shape of nanoplates.…”

Structure and electrochemical behaviors of spherical Li1+xNi0.5Mn0.5O2+δ synthesized by rheological phase reaction method

“…Rheological phase reaction method is a process for preparing compounds or materials from a solid-liquid rheological mixture. The rheological phase reaction method is a simple, economical and efficient soft chemistry method to prepare various functional materials [34][35][36][37][38]. In the rheological phase state, because the solid particles and liquid phase were uniformly distributed, the surface area of solid particles can be efficiently utilized, and the contact between solid particles and fluid is close and uniform [37].…”

“…The rheological phase reaction method is a simple, economical and efficient soft chemistry method to prepare various functional materials [34][35][36][37][38]. In the rheological phase state, because the solid particles and liquid phase were uniformly distributed, the surface area of solid particles can be efficiently utilized, and the contact between solid particles and fluid is close and uniform [37]. The aim of this paper is to develop the rheological phase reaction method to synthesize the Li 1+x Ni 0.5 Mn 0.5 O 2+d materials, and study the effect of lithium content on crystal structure, particle morphology, electrochemical properties (2.5-4.5 V) and safety characteristics of Li 1 +x Ni 0.5 Mn 0.5 O 2+d compounds.…”

Frequency-temperature dependent dynamics of dielectrics in ferric oxoborate Fe3BO6 of cocktail structure of nanorods

“…The compound Fe 3 BO 6 belongs to an important family of iron oxoborates Fe 2þ Fe 3þ OBO 3 , Fe 2þ 2 Fe 3þ O 2 BO 3 , or Fe 3þ 2 Fe 3þ O 3 BO 3 and displays highly tailored electronic properties depending on iron valence Fe 2þ , Fe 3þ , and relative O 2À number density in a space lattice [1][2][3][4][5][6][7][8]. A canted antiferromagnet of 3d 5 (Fe 3þ ) spins on an infinitely large space lattice Fe 3 BO 6 displays a magnetic orientational phase transition from one weak ferromagnet state À 2 to another À 4 [3,9].…”