Synthesis of Nano Silicon Using Lasers

Abstract

Two lasers of the same wavelength (1.06 μm) and various specifications were employed to synthesize silicon nanoparticles. The experimental data reveal the formation of stable silicon nanoparticles with different features such as UV-vis absorption, photoluminescence spectrum, Raman spectrum, Zeta potential, and SEM morphology. Theoretical simulations using COMSOL software were adopted to estimate the surface temperature distribution at the silicon surface and underneath. It is found that maximum temperatures of about (5700 K) and (4600 K) were generated when a Q-switched laser pulse of (10 ns) and fiber laser pulse of (127 ns) were used, respectively. While the recoil pressure at the silicon surface was (6.5*105 N/m2) and (1*103 N/m2) when Nd:YAG and fiber laser were used respectively. It found that increasing the laser energy for Nd:YAG laser and fiber laser power leads to a blue shift of the absorption spectra while the absorption intensity increases with the number of laser pulses and irradiation time. Raman spectroscopy for the prepared silicon nanoparticles was carried out. The Raman peaks for silicon nanoparticles reveal the formation of amorphous silicon. These peaks were observed at (482) and (475 cm-1) when Nd:YAG and fiber lasers were used to produce those nanoparticles. While the photoluminescence of the prepared silicon nanoparticles exhibits peaks at (457 nm) and (495 nm) for Nd:YAG and fiber lasers. The zeta potential reveals that silicon nanoparticle stability is greater for nanoparticles produced by fiber lasers (27 mv) than those produced by Nd:YAG lasers (17 mv) for three months. The corresponding silicon nanoparticle sizes refer to (3.8 nm) and (6 nm). Potential applications of silicon nanoparticles in optoelectronics and biological imaging can be conducted due to the controllable laser micro/nano machining process.