Synthesis of nano magnetic supported NHC-palladium and investigation of its applications as a catalyst in the Mizoroki-Heck cross-coupling reaction in H2O

Abstract

The unique properties of N-heterocyclic carbenes (NHCs) as an effective ligand for palladium catalytic centers have recently found much attention. In this work, Fe 3 O 4 nanoparticle supported palladium(II)–N-heterocyclic carbene catalyst was successfully designed, synthesized and characterized by various methods. The activity of the catalyst was evaluated in the Mizoroki-Heck cross-coupling reaction in which the desired products were obtained in high yield in H 2 O as a green solvent. The reaction was carried out in short reaction times using low amounts of the catalyst. Moreover, the catalyst was easily separated from the reaction media and reused for 5 cycles.