Synthesis of multifunctional polymer containing Ni‐Pd NPs via thiol‐ene reaction for one‐pot cascade reactions

Abstract

Recently, acid–base bifunctional catalysts have been considered due to their abilities, such as the simultaneous activation of electrophilic and nucleophilic species and their high importance in organic syntheses. However, the synthesis of acid–base catalysts is problematic due to the neutralization of acidic and basic groups. This work reports a facial approach to solve this problem via the synthesis of a novel bifunctional polymer using inexpensive materials and easy methods. In this way, at the first step, heterogeneous poly (styrene sulfonic acid‐n‐vinylimidazole) containing pentaerythritol tetra‐(3‐mercaptopropionate) (PETMP) and trimethylolpropane trimethacrylate (TMPTMA) cross‐linkers were synthesized in the pores of a mesoporous silica structure using click reaction as a novel bifunctional acid–base catalyst. After that, Ni‐Pd nanoparticles supported on poly (styrenesulfonic acid‐n‐vinylimidazole)/KIT‐6 as a novel trifunctional heterogeneous acid–base‐metal catalyst was prepared. The prepared catalysts were characterized by various techniques like FT‐IR, TGA, ICP‐AES, DRS‐UV, TEM, FE‐SEM, EDS‐Mapping, and XRD. The synthesized catalysts were efficiently used as bifunctional/trifunctional catalysts for one‐pot, deacetalization‐Knoevenagel condensation and one‐pot, three‐step and a sequential reaction containing deacetalization‐Knoevenagel condensation‐reduction reaction. It is important to note that the synthesized catalyst showing high chemo‐selectivity for the reduction of nitro group, alkenyl double bond and ester group in the presence of nitrile. Moreover, it was found that the different nanoparticles including Ni, Pd, and alloyed Ni‐Pd showing different chemo‐selectivity and catalytic activity in the reaction.

Enhanced catalytic performance of Pd‐Ga bimetallic catalysts for 2‐ethylanthraquinone hydrogenation

“…The isotherms of the samples show type IV curve characteristics with obvious H 3 hysteresis loop, indicating typical mesoporous structures (Figure S1). As shown in Table , all the samples exhibit a mesoporous structure with a pore diameter range of 11.8–12.1 nm. Compared to γ‐Al 2 O 3 , the surface area and the pore volume of the catalysts decrease slightly because of the pore blockage during the catalyst preparation process .…”

PdO nanoparticles supported on triazole functionalized porous triazine polymer as an efficient heterogeneous catalyst for carbonylation of aryl halides

“…It's attributed to the binding energy of C=N for triazine ring, ‐N=N‐and N‐H for triazole ring nitrogen. The N1 s core level clearly shows that triazole was successfully functionalized into the porous triazine polymeric supported materials …”

Amphiphilic Polymer Nanoreactors for Multiple Step, One-Pot Reactions and Spontaneous Product Separation

“…Acid-base bifunctional crosslinked polymers have also been incorporated into the pores of mesoporous silica and combined with Ni or Ni–Pd alloy nanoparticles. The multifunctional catalyst system was used for the three-step, one-pot reaction of a deacetalization-Knoevenagel condensation reduction reaction [ 8 ]. An alternative approach has been incorporating multiple catalysts into a polymer-based nanocarrier.…”