2022
DOI: 10.1016/j.jechem.2022.04.039
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Synthesis of multicore-shell FeS2@C nanocapsules for stable potassium-ion batteries

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Cited by 51 publications
(26 citation statements)
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“…S11, † the peak is divided into C-C/CvC (284.8 eV), C-O/C-N (286.2 eV), and O-CvO bonds (288 eV), respectively. 46 To adsorb the easily soluble polysulfides during charging and discharging, we coated CoS 2 /NC@1T MoS 2 on the positive-facing side to form a modified functionalized separator (Fig. 4).…”
Section: Resultsmentioning
confidence: 99%
“…S11, † the peak is divided into C-C/CvC (284.8 eV), C-O/C-N (286.2 eV), and O-CvO bonds (288 eV), respectively. 46 To adsorb the easily soluble polysulfides during charging and discharging, we coated CoS 2 /NC@1T MoS 2 on the positive-facing side to form a modified functionalized separator (Fig. 4).…”
Section: Resultsmentioning
confidence: 99%
“…Lithium-ion batteries (LIBs) have been extensively used in electronic equipment, electric vehicles, and hybrid electric vehicles due to their high energy density, environmental protection, and long cycling life. Sodium-ion batteries (SIBs) and potassium-ion batteries (PIBs) have attracted great attention in recent years thanks to their abundant natural storage (2.36 and 2.09% for sodium and potassium, respectively, compared to 0.0017% for lithium in weight in the Earth’s crust). PIBs have a lower redox voltage (−2.93 K + /K vs E 0 ) compared to that of SIBs (−2.71 Na + /Na vs E 0 ) and a higher operating voltage and energy density. Besides, with the weaker Lewis acidity of K + , the smallest solvated K + , and Stokes’ radius (0.36, 0.46, and 0.48 nm for K + , Na + , and Li + , respectively), K + has faster diffusion in the electrolyte, thus improving the electrode kinetic. , Unfortunately, the large radius of K + results in the poor kinetic and unstable structure during the depotassiation/potassiation process, leading to low capacity and inferior cycling life. To date, the investigation of PIB electrode materials is also less. On the one hand, the anode materials focus on carbon, graphene, and transition-metal composites. On the other hand, the cathode materials concentrated in Prussian blue and phosphate. , …”
Section: Introductionmentioning
confidence: 99%
“…15,16 Manufacturing nanostructural TMDs with a carbon framework is an effective way to improve their potassium storage performance. For example, ultrasmall CoS 2 nanoparticles integrated into hierarchical porous carbon nanobers, 17 FeS 2 nanoparticles encapsulated in a hollow carbon shell, 18 and ultrane SnS nanoparticles in hollow multichannel carbon nanobers 19 are all promising anode materials for PIBs.…”
Section: Introductionmentioning
confidence: 99%