“…Except for the A 2 B 2 O 7 -type (A = rare earth element, B = Zr, Ce, Hf, Sn) oxides [1][2][3][4][5][6][7][8][9][10], the cerium oxides with fluorite structure have recently attracted extensive attention due to a diversity of applications, such as conversion catalysts for selective hydrogenation of unsatured compounds, catalysts for three-way automobile exhaust systems, abrasives for chemical polishing slurries, gates for metal-oxide semiconductor devices, and luminescent materials for violet/blue fluorescence [12][13][14]. Now, the rare earth doped CeO 2 (RE 2 O 3 -CeO 2 ) have also been considered to be new materials for TBCs and solid oxide fuel cells due to the excellent electrical, mechanical, and thermophysical properties [15][16][17]. For example, Cao et al [18] [21].…”