Synthesis of MOF-Derived Hybrids for Efficient Electrocatalytic Reduction of CO2 to Syngas

MOF-derived transition metal-based catalysts for the electrochemical reduction of CO2to CO: a mini review

“…In the study of bimetallic Ni–Cu nanoparticles anchored in N-doped carbon (NC) derived from ZIF-8 for the CO 2 RR. 140 The synergistic effect of Ni and Cu in the as-prepared Ni Cu-1 catalyst yielded a lower onset potential and higher current density compared with Ni NC and Cu NC. The incorporation of Cu into the catalyst system was also revealed to shift the bond energy of Ni Cu-1 pyridine N to a lower energy region and helped produce syngas with tuneable composition.…”

Electrochemical CO2reduction with ionic liquids: review and evaluation

“…Syngas compositing of H 2 and CO, as an important feedstock in industry, is mainly derived from coal or natural gas, which are non-renewable resources. [97][98][99] CO 2 R potentially provided a more energy-efficient method to produce syngas with different ratios by adjusting the reaction environment, including the electrolyte and catalyst. [100][101][102][103][104][105][106] Among them, H 2 /CO with a ratio of 1 : 1, i.e., H 2 /CO (1 : 1) is suitable for the Fischer-Tropsch hydrocarbon synthesis, while H 2 /CO (2 : 1) can be used to synthesize formaldehyde via hydroformylation.…”

“…Syngas compositing of H 2 and CO, as an important feedstock in industry, is mainly derived from coal or natural gas, which are non-renewable resources. 97–99 CO 2 R potentially provided a more energy-efficient method to produce syngas with different ratios by adjusting the reaction environment, including the electrolyte and catalyst. 100–106 Among them, H 2 /CO with a ratio of 1 : 1, i.e.…”