Synthesis of metal‐containing Schiff based cyclomatrix polyphosphazene microspheres based on polyoxometalates and application in flame retardance for epoxy resin
Abstract:A novel kind of polyoxometalate (POM) ‐containing Schiff based polyphosphazene microspheres (PSPMs) were successfully prepared through the polycondensation between POM‐containing polyaldehyde and 4,4′‐diaminodiphenylmethane. The PSPMs attained excellent thermal stability and demonstrated good monodispersity with a diameter of about 400 nm. In this work, the fire resistance of PSPMs was investigated in the epoxy resin (EP) matrices. Notably, the PSPMs displayed good distribution in EP matrices. Therefore, the d… Show more
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