Synthesis of Macrolides with Hydrazide Fragments from Tetrahydropyran and 2,6-Pyridinedicarboxylic Acid

Yakovleva, M. P.; Shutova, M. A.; Муслухов, Р. Р.; Viripaev, Evgeny M.; Толстиков, А. Г.

doi:10.6060/mhc140374y

Cited by 3 publications

(1 citation statement)

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“…[1][2][3] Besides well-known methods of obtaining macroheterocycles [4][5][6][7] there are methods based on catalytic reactions of diazocarbonyl compounds and they are currently becoming more important. This became possible, primarily, due to the fact that the intermediate carbenes show highly electrophilic properties and readily form ylides with heteroatom compounds.…”

Section: Introductionmentioning

confidence: 99%

Diazo Compounds in the Synthesis of O- and S-Containing Macroheterocycles

Раскильдина¹,

Zlotsky²,

Sultanova³

2018

MHC

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The review summarizes, systematizes and analyzes literature data of the synthesis of oxygen-and sulfur-containing macroheterocyclic systems using Rh and Cu-catalyzed reactions of diazocarbonyl compounds over the last 15-20 years. The review considers the intra-and intermolecular reactions of introduction of diazocarbonyl compounds, which are used in synthesis of practically important biologically active compounds, via the C-O and C-S bonds.Keywords: Carbenoids, α-diazo carbonyl compounds, O,S-macroheterocycles, cyclic acetals, C-O and C-S insertions, catalysis, ylides. Диазосоединения в синтезе О -и S -содержащих макрогетероциклов

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