2022
DOI: 10.6023/cjoc202201015
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Synthesis ofβ-Oxopropylcarbamates Catalyzed by ZnO/Ionic Liquids under Atmospheric CO2

Abstract: Carbamate compounds exhibit a broad applicable scope in medicine, pesticide, resin modification, fabric finishing and organic synthesis. A methodology using ZnO/ionic liquids as the catalyst for the three-component coupling reactions of carbon dioxide (CO2), secondary amines and propargylic alcohols to produce various β-oxopropylcarbamates was developed. This catalytic system exhibited robust recyclability and broad substrate scope. Moreover, it showed considerable catalytic activity under atmospheric CO2, ind… Show more

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