Synthesis of hydroxy- and dihydroxy-end-capped poly(n-butyl acrylate)s and their use as reactive stabilizers for the preparation of polyurethane latexes

The aim of this article is to report the creation of artificial, robust, and very hydrophobic materials with core-shell polyurethane-polydimethylsiloxane or polyurethane-poly(n-butyl acrylate) polymer microparticles. These latexes were prepared by polyaddition in cyclohexane with commercial or synthetic steric stabilizers. An easy onestep method based on the filtration of the colloidal particles was developed to obtain water-repellent fibrous materials such as paper or textiles that maintain stable properties even after several washing/drying cycles.

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“…15,16 In this article, PnBA-OH of 13,000 g/mol was synthesized and used as a reactive steric stabilizer.…”

Section: Methodsmentioning

confidence: 99%

“…[15][16][17][18] The stabilization of the precipitating polymer is due to the presence of a reactive polymer (surfmer) in the dispersant phase, which reacts with the growing polymer and remains covalently bonded to the final particle. The obtained dispersion is a latex.…”

Section: Introductionmentioning

confidence: 99%

Simple route to get very hydrophobic surfaces of fibrous materials with core–shell latex particles

Nguyen

Chambon

Rosselgong

et al. 2008

J of Applied Polymer Sci

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“…This is in accordance with our previous investigations, where we observed that polymerizations achieved under similar conditions in the presence of PDMSOH did not lead to the formation of particles. Such behavior may be compared to the one observed for dispersions carried out in cyclohexane in the presence of PSOH or PnBuAOH (used as surfmers), for which a coagulation phenomenon was observed 20, 21, 34, 35. In order to overcome this problem, hydroxy‐terminated PFDA were derivatized into isocyanate terminated ones by reacting PFDAOH with the desired amount of TDI.…”

Section: Resultsmentioning

confidence: 99%

Synthesis of Polyurethane/Poly(1,1,2,2‐tetrahydroperfluorodecyl acrylate) Particles in Supercritical Carbon Dioxide

Renault

Cloutet

Lacroix‐Desmazes

et al. 2008

Macro Chemistry & Physics

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A new range of end‐functionalized poly(1,1,2,2‐tetrahydroperfluorodecyl acrylate)s was synthesized by ATRP. Such macromonomers were used as reactive and steric stabilizers for the preparation of original core‐shell polyurethane particles in supercritical carbon dioxide. The nature of the chain end functionality, as well as the molar mass of the reactive stabilizer, were varied in order to investigate the role of such parameters on the properties of the resulting materials. Due to the low surface energy of PFDA combined with the high surface roughness induced by the specific microstructure of particles deposited on a silica plate, PUR materials exhibited super‐hydrophobic behavior with a water CA above 150°.magnified image

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“…A series of a,a 0 -di-hydroxyl poly(n-butyl acrylate) (PBA(OH) 2 ) were prepared by ATRP with CuBr/PMDETA as a catalytic system according to references [8][9][10][11].…”

Section: Methodsmentioning

confidence: 99%

Relationship between Architecture and Adhesive Properties of Macromolecular Materials, 1

Baron

Cloutet

Cramail

et al. 2003

Macro Chemistry & Physics

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This study deals with the preparation of polyurethane‐graft‐poly(n‐butyl acrylate)s copolymers by polymerization of diphenyl‐methane‐4,4‐di‐isocyanate (MDI) with α,α′‐di‐hydroxyl‐poly(n‐butyl acrylate)s of different sizes as macromonomers. The polyaddition has been studied on the basis of kinetic measurements, and the comb‐like structure of the resulting polymer has been well‐established. Such grafted copolymers display specific adhesive properties in connection with their comb‐like architecture.magnified image

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Synthesis of hydroxy- and dihydroxy-end-capped poly(n-butyl acrylate)s and their use as reactive stabilizers for the preparation of polyurethane latexes

Cited by 24 publications

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Simple route to get very hydrophobic surfaces of fibrous materials with core–shell latex particles

Simple route to get very hydrophobic surfaces of fibrous materials with core–shell latex particles

Synthesis of Polyurethane/Poly(1,1,2,2‐tetrahydroperfluorodecyl acrylate) Particles in Supercritical Carbon Dioxide

Relationship between Architecture and Adhesive Properties of Macromolecular Materials, 1

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