2010
DOI: 10.1039/c0jm01799j
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Synthesis of highly nitrogen-doped hollow carbon nanoparticles and their excellent electrocatalytic properties in dye-sensitized solar cells

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Cited by 130 publications
(91 citation statements)
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“…[ 13 ] In contrast to Pt, carbon-based materials can be produced in scalable quantity at low cost, and they have better corrosion stability in DSSCs. As a result, carbon blacks, [ 14 ] carbon nanoparticles, [ 15 ] carbon nanotubes, [ 16,17 ] and graphene nanosheets [18][19][20][21][22] have been widely studied in hopes of fi nding promising alternatives to Pt-based materials. Their electrocatalytic activities are not comparable to Pt for the conventional I − /I 3 − redox couple, but graphene-based CEs outperformed the conventional Pt CEs in the Co-based mediators that have been reported.…”
mentioning
confidence: 99%
“…[ 13 ] In contrast to Pt, carbon-based materials can be produced in scalable quantity at low cost, and they have better corrosion stability in DSSCs. As a result, carbon blacks, [ 14 ] carbon nanoparticles, [ 15 ] carbon nanotubes, [ 16,17 ] and graphene nanosheets [18][19][20][21][22] have been widely studied in hopes of fi nding promising alternatives to Pt-based materials. Their electrocatalytic activities are not comparable to Pt for the conventional I − /I 3 − redox couple, but graphene-based CEs outperformed the conventional Pt CEs in the Co-based mediators that have been reported.…”
mentioning
confidence: 99%
“…A method formed carbon shells on silica nanoparticles templates under extreme heat which was etched away using harsh chemicals [8]. Nitrogen doped hollow carbon nanoparticles have been assembled by detonation-assisted chemical vapor deposition method [9,10]. Hollow fluorescent carbon nanoparticles were produced by the carbonization of acetic acid using a highly exothermic reaction between water and P 2 O 5 , which only formed cross-linked carbon nanoparticles [11].…”
mentioning
confidence: 99%
“…These could be attributed to the large void space yielded from the removal of iron nanoparticles, which is in good agreement with TEM results. Remarkably, a sharp drop at P/P 0 = 0.5 in the desorption branch of GCS-1000 (after Fe removal) depicts the phenomenon of a large pore encapsulated by a matrix with relatively small pore sizes [20,21]. Therefore, hierarchical pore size distribution in the micro-and macroporous regions is recognized, which endows a high the BET surface area of 381 m 2 g -1 and a large pore volume of 0.45 cm 3 g -1 for GCS-1000 (after Fe removal).…”
Section: Resultsmentioning
confidence: 95%