Synthesis of high nitrogen doping of carbon nanotubes and modeling the stabilization of filled DAATO@CNTs (10,10) for nanoenergetic materials

Highly energetic compositions based on functionalized carbon nanomaterials

“…For instance, CNTs (10,10) were selected as a nanoscale matrix to host N-oxides of 3,3′-azo-bis(6-amino-1,2,4,5-tetrazine) (DAATO) molecules, using a CVD (chemical vapor deposition) method for obtaining so-called nitrogen-doped CNTs (N-CNTs). 232 Their SEM and TEM images, as well as XPS spectra are shown in Fig. 31.…”

Facile one-pot synthesis of platinum nanoparticles decorated nitrogen-graphene with high electrocatalytic performance for oxygen reduction and anodic fuels oxidation

“…(~399.6eV) and larger amount of quaternary graphitic type N atoms (~401.0eV) [17,28,29,44]. As mentioned above, the graphitic quaternary nitrogen, plays a significant role in the high electrocatalytic activity for ORR [13,[26][27][28][29], with higher CO and methanol poisoning resistance.…”

Reactivity Indexes and Structure of Fullerenes

“…Currently, the most notable examples have been studies of N@C 60 , N@C 70 or even N 2 @C 60 [48][49][50][51][52], which have extended the use of the C 60 cage as a way of confining up to 16 nitrogen atoms [53,54]. Also recently, the encapsulation of a polymer nitrogen chain in a carbon nanotube was conceived, as in principle this could be stable up to room temperature [55]. This contrasts with other proposed polynitrogenated phases of nitrogen that have been inspired by the analogy to phosphorus and arsenic, all superior in energy to the "cubic gauche" (CG).…”