Synthesis of functionalized iron N-heterocyclic carbene complexes and their potential application as flame behavior modifier in cross linked epoxy resins

(Cyclopentadienone)iron Complexes: Synthesis, Mechanism and Applications in Organic Synthesis

“…Simultaneously, Mazzoni and co‐workers [162] also reported an efficient strategy for synthesis of iron‐NHC complexes, which involves transmetallation between nitrile ligated CPDICs and in situ generated silver‐NHC complexes. Later, they functionalized these complexes by introducing a pendant amino group in the carbene ligand in order to influence its steric, electronic and solubility properties [163,164] . The photophysical properties were exclusively studied in both organic and aqueous solvents.…”

Iron integrated carbon nitride: A recoverable heterogeneous catalyst for the construction of bis (hetero/homoarylidene)cycloalkanones

“…37 Generally, in order to heterogenize iron catalysts, a solid matrix including silica, alumina, or polymers have been employed. [38][39][40][41][42][43][44][45][46][47][48] However, inorganic metal oxides are hard and heavy when compared with soft organic support materials. In an organic solvent, an organic catalyst powder can mix better than inorganic material.…”

“…Hence, homogeneous catalyst is not favored towards industrial applications 37 . Generally, in order to heterogenize iron catalysts, a solid matrix including silica, alumina, or polymers have been employed 38–48 . However, inorganic metal oxides are hard and heavy when compared with soft organic support materials.…”

Electrochemical polymerisation of newly synthesised 3,4-ethylene dioxythiophene-N-heterocyclic carbene iron complexes and application as redox mediators

“…[8][9][10][11] Immobilization through ionic or covalent bond is a good tool to exploit the high activity and specific properties of transition metal molecular complexes. 2,[12][13][14][15][16] While this approach has been studied in the last two decades in order to obtain single site iron based molecular catalysts for olefin polymerization [17][18][19][20][21] alkenes and alkanes oxidation, 22,23 hydrogenation 24 and Michael addition reactions, 25 it has recently become an innovative approach for the development of more efficient electrochemical devices. Indeed, chemically modified electrodes are widely employed in electrochemistry and an important goal in this field is to find a way to strongly anchor redox mediators on the electrode surface (e.g.…”