Nanoscience and Nanotechnology suggest that many of the current problems involving water quality can be solved or greatly ameliorated using the nanoscale adsorbents, called nanoadsorbents. Innovations in the development of novel carbon nanomaterials like fullerenes, carbon nanotubes, and graphene are among the most exciting and promising materials for water treatment-purification. This chapter gives detailed description of the structure, morphology, and adsorption properties of carbon nanoadsorbents. The textural properties of fullerene, carbon nanotubes, and graphene family are highlighted. A brief description of the effects of the electronic properties in the adsorption capability was inferred as well as how the adsorption of molecules may affect photoelectronic properties of carbon nanotubes.