Synthesis of diquinolinoanthracene and pyridonoanthraquinolines

Kazankov, M. V.; Bernadskii, M. I.; Mustafina, M. Ya.

doi:10.1007/bf00506972

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2016

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“…Acid-catalyzed cyclizations of anthraquinone and anthrapyridone derivatives, reported by Kazankov, Bernadskii, and Mustafina, yielded benzannulated 1,8-diazapyrenes shown in Scheme 88. 486 Specifically, compound 88.8 was prepared in two steps, by refluxing 88.6 in polyphosphoric acid and subsequent heating of the intermediate 88.7 in the presence of aniline. The overall yield of the latter sequence was improved to 64% when the order of steps was reversed.…”

Section: Chemical Reviewsmentioning

confidence: 99%

Heterocyclic Nanographenes and Other Polycyclic Heteroaromatic Compounds: Synthetic Routes, Properties, and Applications

et al. 2016

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Two-dimensionally extended, polycyclic heteroaromatic molecules (heterocyclic nanographenes) are a highly versatile class of organic materials, applicable as functional chromophores and organic semiconductors. In this Review, we discuss the rich chemistry of large heteroaromatics, focusing on their synthesis, electronic properties, and applications in materials science. This Review summarizes the historical development and current state of the art in this rapidly expanding field of research, which has become one of the key exploration areas of modern heterocyclic chemistry.

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Section: Chemical Reviewsmentioning

confidence: 99%