Synthesis of Decorated Carbon Structures with Encapsulated Components by Low-Voltage Electric Discharge Treatment

Abstract

Polycondensation of complexes of chloromethanes with triphenylphosphine by the action of low-voltage electric discharges in the liquid phase gives nanosized solid products. The elemental composition involving the generation of element distribution maps (scanning electron microscopy–energy dispersive X‑ray spectroscopy mapping) and the component composition (by direct evolved gas analysis–mass spectrometry) of the solid products have been studied. The elemental and component compositions of the result-ing structures vary widely depending on the chlorine content in the substrate and on the amount of triphenylphosphine taken. Thermal desorption analysis revealed abnormal behavior of HCl and benzene present in the solid products. In thermal desorption spectra, these components appear at an uncharacteristically high temperature. The observed anomaly in the behavior of HCl is due to HCl binding into a complex of the solid anion $${\text{HCl}}_{2}^{ - }$$ with triphenyl(chloromethyl)phosphonium chloride, which requires a relatively high temperature (up to 800 K) to decompose. The abnormal behavior of benzene is associated with its encapsulated state in nanostructures. The appearance of benzene begins at 650 K and continues up to temperatures above 1300 K.

Molecular motion of a nanoscopic moonlander via translations and rotations of triphenylphosphine on graphite

“…For example, phosphorus-doped graphene nanosheets can be prepared via annealing of graphene oxide in the presence of PPh 3 . These nanosheets show excellent NH 3 sensing ability at room temperature 10 , 11 . Moreover, it was shown that the preparation of PPh 3 -modified graphene quantum dots gives rise to a high quantum yield and excellent stability 12 .…”