Synthesis of dark Li4−3xFexSiO4 for simultaneous direct solar thermal conversion and durable thermochemical energy storage

Fu, Ruicheng; Huang, Jingchun; Feng, Qiannian; Liu, Ding; Hu, Yingchao

doi:10.1016/j.est.2023.109053

Cited by 2 publications

(1 citation statement)

References 52 publications

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“…For example, doping K 2 CO 3 in Li 4 SiO 4 could turn the Li 2 CO 3 solid shell to eutectic Li 2 CO 3 -K 2 CO 3 during Li 4 SiO 4 -CO 2 reactions, thus reducing the diffusion resistance of CO 2 molecules and making the reaction more sufficient [28,29]. The introduction of heteroatoms in Li 4 SiO 4 , like Fe-doping or Ce-addition, could form lattice defects or inert skeletons, thus increasing both the reaction capacity and the cyclic stability of the Li 4 SiO 4 heat carrier significantly [30,31]. The optimization of synthetic processes could also improve the performance of the obtained Li 4 SiO 4 , especially the selection of raw materials.…”

Section: Introductionmentioning

confidence: 99%

Li4SiO4-Based Heat Carrier Derived from Different Silica Sources for Thermochemical Energy Storage

Wang,

Xia,

et al. 2024

Energies

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Thermochemical energy storage (TCES) is one of the key technologies facilitating the integration of renewable energy sources and mitigating the climate crisis. Recently, Li4SiO4 has been reported to be a promising heat carrier material for TCES applications, owing to its moderate operation temperature and stability. During the synthetic processes, the properties of the Si source used directly influence the performance of derived Li4SiO4 materials; however, the internal relations and effects are not yet clear. Hence, in this work, six kinds of SiO2 sources with different phases, morphology, particle size, and surface area were selected to synthesize a Li4SiO4-based TCES heat carrier. The physicochemical properties of the SiO2 and the corresponding derived Li4SiO4 were characterized, and the comprehensive performance (e.g., heat storage/releasing capacity, rate, and cyclic stability) of the Li4SiO4 samples was systematically tested. It was found that the silica microspheres (SPs), which possess an amorphous phase, uniform micro-scale structure, and small particle size, could generate Li4SiO4 TCES materials with a highest initial capacity of 777.7 kJ/kg at 720 °C/900 °C under pure CO2. As a result, the SP-L showed an excellent cumulative heat storage amount of 5.84 MJ/kg within 10 heat-releasing/storage cycles, which was nearly 1.5 times greater than the value of Li4SiO4 derived from commonly used silicon dioxide. Furthermore, the effects of the utilized Si source on the performance of as-prepared Li4SiO4 and corresponding mechanisms were discussed, which offers guidance for the future selection of Si sources to produce high-performance Li4SiO4-based TCES heat carriers.

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