Synthesis of cyclic carbonates and dimethyl carbonate using CO2 as a building block catalyzed by MOF-5/KI and MOF-5/KI/K2CO3

Song, Jinliang; Zhang, Binbin; Jiang, Tao; Yang, Guanying; Han, Buxing

doi:10.1007/s11458-011-0225-x

Cited by 27 publications

(13 citation statements)

References 49 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Han et al 27 reported that metal organic frameworks (MOFs) gave high conversions to cyclic carbonates when used as a cocatalyst. MOF-5 was investigated (comprised of Zn 4 O(BDC) 3 , where BDC is benzene-1,4-dicarboxylate).…”

Section: Alkali Metals (Sodium and Potassium)mentioning

confidence: 99%

Sustainable metal-based catalysts for the synthesis of cyclic carbonates containing five-membered rings

et al. 2015

View full text Add to dashboard Cite

show abstract

Section: Alkali Metals (Sodium and Potassium)mentioning

confidence: 99%

Sustainable metal-based catalysts for the synthesis of cyclic carbonates containing five-membered rings

et al. 2015

View full text Add to dashboard Cite

show abstract

“…The synergistic effect of MOF‐5 and n ‐BuN 4 Br was believed to be the main reason for the high catalytic activity of the catalytic system under mild conditions. The same group reported MOF‐5/KI as an effective catalyst for the cycloaddition of CO 2 and propene oxide to produce propene carbonate …”

Section: Mofs: Structural Characteristics and Catalytic Performancementioning

confidence: 99%

Porous crystals as active catalysts for the synthesis of cyclic carbonates

Zhu

Carreón

2013

J of Applied Polymer Sci

View full text Add to dashboard Cite

REVIEWSABSTRACT: The utilization of CO 2 as a renewable raw material for the production of chemicals is an area of great societal importance. In particular, the catalytic conversion of CO 2 into cyclic carbonates, which are useful chemical intermediates used for the production of plastics and organic solvents, represents an appealing approach for the efficient use of CO 2 . Microporous crystals, such as zeolites and metal organic frameworks, and ordered mesoporous phases have emerged as novel porous materials that combine highly desirable properties, such as uniform pores on the microscale and mesoscale, high surface areas, flexible chemistries, and exceptional thermal and chemical stability; this makes them ideal candidates for catalytic applications. In this review, representative examples demonstrating the catalytic ability of these porous materials for the synthesis of cyclic carbonates from CO 2 are presented. The fundamental structure/catalysis relationships of these porous phases in the conversion of CO 2 into cyclic carbonates are discussed. V C 2013Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014, 131, 39738.

show abstract

“…46,47 However, in the case of MOF-5 grown around the fibers, the strong peaks around 1390 and 1600 cm –1 are assigned to the existence of organic linker, which is in the case of MOF-5 terephthalic acid. 48…”

Section: Resultsmentioning

confidence: 99%

Crystal Growth of Metal–Organic Framework-5 around Cellulose-Based Fibers Having a Necklace Morphology

et al. 2019

View full text Add to dashboard Cite

Herein, metal–organic framework (MOF)-5 crystals were grown on cellulose-based substrates including paper and cotton. Dopamine was used as a surface modification agent to improve the compatibility between MOF-5 crystals and the used substrates. The formed polydopamine film promoted the growth of MOF-5 crystals, which were bonded to the substrates. Besides dopamine, the structure of the substrate also played a major role in the crystal growth. In the case of paper, which had a structure with fibers closely packed to each other, MOF-5 crystals grew only on the surface of fibers (one side) and could easily fall off. Unlike paper, the cotton bulb had a looser structure and MOF-5 crystals grew around the fibers, forming a stable “necklace” morphology. The effects of dopamine modification on the crystal growth and the formation of “necklace” morphology were investigated using scanning electron microscopy analysis. The crystalline structure of MOF-5 was confirmed using X-ray diffraction. To determine how firmly crystals were attached to the cotton fibers, the substrates were exposed to a constant and strong air flow. It was found that the dopamine-modified cotton increased the strength of MOF-5 crystals attached to fibers. This work demonstrated the firm attachment of MOF-5 crystals onto the substrate, facilitating various potential applications.

show abstract

Synthesis of cyclic carbonates and dimethyl carbonate using CO2 as a building block catalyzed by MOF-5/KI and MOF-5/KI/K2CO3

Cited by 27 publications

References 49 publications

Sustainable metal-based catalysts for the synthesis of cyclic carbonates containing five-membered rings

Sustainable metal-based catalysts for the synthesis of cyclic carbonates containing five-membered rings

Porous crystals as active catalysts for the synthesis of cyclic carbonates

Crystal Growth of Metal–Organic Framework-5 around Cellulose-Based Fibers Having a Necklace Morphology

Contact Info

Product

Resources

About