Synthesis of core–shell imprinting polymers with uniform thin imprinting layer via iniferter-induced radical polymerization for the selective recognition of thymopentin in aqueous solution

Abstract

Core–shell imprinting microspheres for the selective and rapid recognition of thymopentin with the aid of a novel polymeric ionic liquid.

Microwave-assisted rapid synthesis of a polyether from a plant oil derived monomer and its optimization by Box–Behnken design

“…The peaks observed in the spectrum at about 529, 282, and 101 eV are due to O 1s and C 1s respectively. 40 Fig. 7 clearly shows that the polyether is composed of carbon and oxygen only.…”

Molecularly Imprinted Materials for Selective Biological Recognition

“…Thus, the imprinting method is similar to the amino acids imprinting. Our group have conducted intensive research on the selective recognition of thymopentin (TP5, Arg‐Lys‐Asp‐Val‐Tyr) and human β‐casein (IHHC, Val‐Glu‐Pro‐Ile‐Pro‐Tyr) etc., by virtue of surface imprinting via radical polymerization, as shown in Figure A,B. However, the small differences between many amino acids and the exchange position of the amino acids on the peptide only produce small changes in the overall properties, which greatly reduces the recognition efficiency of MIPs .…”

“…A) Preparation of surface molecular imprinting for selective recognition of TP5. Reproduced with permission . Copyright 2016, Royal Society of Chemistry; B) schematic diagram of the synthesis of molecularly imprinted microspheres for recognition of IHHC.…”

Synthesis of graft copolymers by combination of radical photopolymerization and iniferter process

“…Unlike the traditional systems, a reversible activation existed in the described process. Over the years, different polymeric architectures were obtained via iniferter approach taking the advantage of the capability of polymerization at relatively low temperatures and no requirement for the further purification steps . Although there exist diverse iniferters like azo compounds, tetraphenylethane, and sulfides, among them triphenylmethane (trityl) derivatives were discovered to be an ideal thermal iniferter providing adequate activation–deactivation cycles to give polymers with narrow molecular weight distribution …”