2001
DOI: 10.1016/s0277-5387(01)00901-9
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Synthesis of copper(II) and nickel(II) complexes using compartmental ligands: X-ray, electrochemical and magnetic studies

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Cited by 66 publications
(31 citation statements)
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“…These results reveal that the carbonyl group of the amino acid ligand was involved in the complex formation. The coordination through the nitrogen of azomethine and oxygen of ν (C-O) of ligand were further evidenced by the appearance of non-ligand bands around 466-504 cm -1 and 528-556 cm -1 were due to M-N and M-O bonds respectively [20,21]. Table 2.IR spectra of ligand and metal complexes…”
Section: Infrared Spectramentioning
confidence: 99%
“…These results reveal that the carbonyl group of the amino acid ligand was involved in the complex formation. The coordination through the nitrogen of azomethine and oxygen of ν (C-O) of ligand were further evidenced by the appearance of non-ligand bands around 466-504 cm -1 and 528-556 cm -1 were due to M-N and M-O bonds respectively [20,21]. Table 2.IR spectra of ligand and metal complexes…”
Section: Infrared Spectramentioning
confidence: 99%
“…The ground state of copper (II) is d x 2 −y 2 , three spin-allowed transitions are expected, [17,18] viz.,…”
Section: Magnetic Moment and Uv-vis Spectramentioning
confidence: 99%
“…22,23 Cyclic voltammetry (CV) studies of the complexes were carried out in 10 mmol/L solutions in DMF containing 0.1 mol/L [NBu 4 ][PF 6 ] as supporting electrolyte. Cyclic voltammograms were performed in a potential range of +1.6 to -2.0 V at sweep rates between 25 and 800 mV/s and were initiated from open circuit potential (E i =0).…”
Section: Electrochemical Measurementsmentioning
confidence: 99%
“…33,34 The magnetic data of the Ni(II) complex agree with a d 8 metal ion in an octahedral configuration. 22,35 …”
Section: 28mentioning
confidence: 99%