Synthesis of Cobalt(III) Ammine Complexes as Explosives for Safe Priming Charges

Preparation, Crystal Structure and Thermal Analyses of a Nitrogen‐rich Coordination Compound [Co(DAT)6](PA)2·4H2O

“…DAT-based energetic salts have become hot issues in recent years. 15,[21][22][23][24] Some work has also been done on complexes with DAT as ligands, 20,[25][26][27][28][29] several of which possess high-energycapacity and are promising primary explosives for safe priming charges. 20,28,29 As a part of our continual effort in energetic transition metal complexes, we herein report on the preparation, structural characterization and thermal decomposition investigation of a new coordination compound [Co(DAT) 6 ]-(PA) 2 •4H 2 O using DAT as ligands and picrate (PA) as outer anions.…”

“…15 Furthermore, they are heterocyclic compounds rich in electron pairs, so they can coordinate with transition-metal ions. The coordination compounds with 5-aminotetrazole [16][17][18] or 1-methyl-5-amino-tetrazole 19,20 as ligands have been studied in the past few years. DAT-based energetic salts have become hot issues in recent years.…”

Porous Silicon Formation by Stain Etching

“…Just as for H 2 O 2 , the kinetics of hole injection from ClO 4 À are so slow as to preclude significant etching (Dudley and Kolasinski 2009a, b (Smirnov et al 2004). In comparison, the expense of Ru(CN) 6 3À and the potential radioactivity of UO 2 + seem appealing.…”

Crystal Structure, Thermal Decomposition Behaviors and Sensitivity Properties of a Novel Energetic Compound [Co(DAT)6] (ClO4)2

“…The complexes which use transition-metal as central anions and DAT as ligand have gained more and more attention in the field of energetic materials. [22][23][24][25][26][27][28][29][30][31] In order to investigate new energetic coordination compounds, a novel complex [Co(DAT) 6 ](ClO 4 ) 2 similar to BNCP structurally was synthesized. The characterization, testing and analysis of [Co(DAT) 6 ](ClO 4 ) 2 are also detailed in this paper.…”