Synthesis of Ce0.1La0.9MnO3 Perovskite for Degradation of Endocrine-Disrupting Chemicals under Visible Photons

Abstract

The UN Environmental Protection Agency has recognized 4-n-Nonylphenol (NP) and bisphenol A (BPA) as among the most hazardous chemicals, and it is essential to minimize their concentrations in the wastewater stream. These industrial chemicals have been witnessed to cause endocrine disruption. This report describes the straightforward hydrothermal approach adopted to produce Ce0.1La0.9MnO3 (CLMO) perovskite’s structure. Several physiochemical characterization approaches were performed to understand the Ce0.1La0.9MnO3 (CLMO) perovskite crystalline phase, element composition, optical properties, microscopic topography, and molecular oxidation state. Here, applying visible photon irradiation, the photocatalytic capability of these CLMO nanostructures was evaluated for the elimination of NP and BPA contaminants. To optimize the reaction kinetics, the photodegradation of NP and BPA pollutants on CLMO, perovskite was studied as a specification of pH, catalyst dosage, and initial pollutant concentration. Correspondingly, 92% and 94% of NP and BPA pollutants are degraded over CLMO surfaces within 120 and 240 min, respectively. Since NP and BPA pollutants have apparent rate constants of 0.0226 min−1 and 0.0278 min−1, respectively, they can be satisfactorily fitted by pseudo-first-order kinetics. The decomposition of NP and BPA contaminants is further evidenced by performing FT-IR analysis. Owing to its outstanding photocatalytic execution and simplistic separation, these outcomes suggest that CLMO is an intriguing catalyst for the efficacious removal of NP and BPA toxicants from the aqueous phase. This is pertinent for the treatment of endocrine-disrupting substances in bioremediation.

An iron metal–organic framework-based electrochemical sensor for identification of Bisphenol-A in groundwater samples

“…Because of its detrimental effects on human health, BPA can lead to a variety of abnormalities in boys' genitalia. 1,2 In addition, it can cause a drop in sperm count in males. 3 It can also trigger breast cancer in females and initiate early sex maturation in girls.…”