“…Four known POAs, isopteropodine (4), pteropodine (5), uncarine F (6), and isopteropodic acid (7) (Figure 1) were also isolated, and their structures characterized by NMR spectroscopy and literature comparison. 16,17 Alkaloid 1 had the molecular formula C 21 H 26 O 5 N 2 from the high-resolution electrospray ionization-mass spectrometry (HRESI-MS) ion peak at m/z 387.1929 [M + H] + (calcd 387.1920) and 13 C NMR data. Thus, it has an additional 18 mass units compared to the known POAs 4, 5, and 6.…”