2008
DOI: 10.1007/s10853-008-2561-x
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Synthesis of Ca3Co4O9 ceramics by polymerized complex and hydrothermal hot-pressing processes and the investigation of its thermoelectric properties

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Cited by 47 publications
(40 citation statements)
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“…One approach to improve the thermoelectric properties is optimisation of the material preparation technique and post treatment. In this regard, several methods have been developed to obtain improved thermoelectric properties [11,23,28,[31][32][33][34]. For example, Lan et al [28] reported a co-precipitation method to prepare fine-grained CaMnO 3 -based ceramics with decreased thermal conductivity due to the enhancement of grain boundary scattering.…”
Section: Introductionmentioning
confidence: 99%
“…One approach to improve the thermoelectric properties is optimisation of the material preparation technique and post treatment. In this regard, several methods have been developed to obtain improved thermoelectric properties [11,23,28,[31][32][33][34]. For example, Lan et al [28] reported a co-precipitation method to prepare fine-grained CaMnO 3 -based ceramics with decreased thermal conductivity due to the enhancement of grain boundary scattering.…”
Section: Introductionmentioning
confidence: 99%
“…Conventional SSR and the sol-gel method are simple techniques in many types of synthesis methods for oxide thermoelectric materials. Many other methods, such as hydrothermal, 67 combustion, 68 sol-gel, 66 etc, are available, but we do not discuss them in detail. For the SrTiO 3 -based materials, we list only the highest figure of merit obtained using each synthesis method in Figure 6.16.…”
Section: Sol-gel and Spsmentioning
confidence: 99%
“…[13], or inventing the novel synthesis method [14][15][16]. Ca 3 Co 4 O 9 was generally prepared by a conventional solid state reaction starting from a mixture of calcium carbonate and cobalt oxide [3,10].…”
Section: Introductionmentioning
confidence: 99%
“…Ca 3 Co 4 O 9 was generally prepared by a conventional solid state reaction starting from a mixture of calcium carbonate and cobalt oxide [3,10]. However, some reports show that the Ca 3 Co 4 O 9 samples synthesized by the sol-gel method have a finer grain size and more uniform size distribution, which are believed to be an important key figures to improve thermoelectric properties [14,16].…”
Section: Introductionmentioning
confidence: 99%