Synthesis of azolyl-substituted adamantane derivatives and their coordination compounds

Pavlov, Dmitry I.; Сухих, Т. С.; Potapov, Аndrei S.

doi:10.1007/s11172-020-2985-2

Cited by 6 publications

(1 citation statement)

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“…Following interest in the coordination chemistry of heterocyclic adamantane derivatives [32][33][34], we have prepared a new ligand 1,3-bis(1,2,4-triazol-1-yl)adamantane (L) and explored its reactions with Cd(II) and Ag(I) ions. As a result, three new Ag(I) and Cd(II) coordination polymers were synthesized and characterized.…”

Section: Introductionmentioning

confidence: 99%

Synthesis, Crystal Structure, and Luminescence of Cadmium(II) and Silver(I) Coordination Polymers Based on 1,3-Bis(1,2,4-triazol-1-yl)adamantane

et al. 2021

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Coordination polymers with a new rigid ligand 1,3-bis(1,2,4-triazol-1-yl)adamantane (L) were prepared by its reaction with cadmium(II) or silver(I) nitrates. Crystal structure of the coordination polymers was determined using single-crystal X-ray diffraction analysis. Silver formed two-dimensional coordination polymer [Ag(L)NO3]n, in which metal ions are linked by 1,3-bis(1,2,4-triazol-1-yl)adamantane ligands, coordinated by nitrogen atoms at positions 2 and 4 of 1,2,4-triazole rings. Layers of the coordination polymer consist of rare 18- and 30-membered {Ag2L2} and {Ag4L4} metallocycles. Cadmium(II) nitrate formed two kinds of one-dimensional coordination polymers depending on the metal-to-ligand ratio used in the synthesis. Coordination polymer [Cd(L)2(NO3)2]n was obtained in case of a 1:2 M:L ratio, while for M:L = 2:1 product {[Cd(L)(NO3)2(CH3OH)]·0.5CH3OH}n was isolated. All coordination polymers demonstrated ligand-centered emission near 450 nm upon excitation at 370 nm.

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Section: Introductionmentioning

confidence: 99%