Synthesis of an aprotic polar polymer with tetrahydrofuran moiety: Copolymer composition control in radical copolymerization with styrene using suspension system
Abstract:A method to control the copolymer composition in suspension polymerizations of monomers with different polarity was studied: the copolymerization of a styrene‐type monomer having THF moiety (1) with styrene (feed ratio 1 : 1) was carried out at 85 °C using benzoyl peroxide (BPO) in a suspension system consisting of water and monochlorobenzene. The copolymerization was greatly affected by a mixture ratio of suspension system, and when the H2O : PhCl ratio was 7 : 1 (v/v), 1 and St were consumed almost at the sa… Show more
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