Abstract:The mixed‐valent, europium borate Eu5(BO3)4 was synthesized from Eu2B2O5 and EuB2O4. Its structure was refined by Rietveld analysis. Eu5(BO3)4 crystallizes in space group Pnma (a=2229.77(2) pm, b=1599.91(2) pm, and c=877.75(1) pm) and was found to be isostructural with Eu5(BO2.51N0.49)4. Powder reflectance spectra (UV/vis/NIR) and magnetic susceptibility data of Eu5(BO3)4 and of the reference compounds EuIIB4O7 and EuIIIBO3 were measured. The spectrum of the mixed ‐valent europium(II, III) borate shows the 7F0→… Show more
Set email alert for when this publication receives citations?
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.