Synthesis of 9-Arylhexahydroacridine-1,8-diones Using Phosphate Fertilizers as Heterogeneous Catalysts

Chehab, Soukaina; Merroun, Youssef; Ghailane, Tourya; Ghailane, Rachida; Boukhris, Saı̈d; Akhazzane, Mohamed; Kerbal, Abdelali; Souizi, Abdelaziz

doi:10.1134/s1070428019090185

Cited by 16 publications

(3 citation statements)

References 39 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…As a continuation of the previous works developed by our researchers [27][28][29][30][31][32][33][34][35][36][37][38][39] , which consist on the valorization of Moroccan phosphates in the field of organic synthesis, and the development of green and sustainable chemistry, this paper reports the first and an easy preparation method for TiP2O7 from the modifications of phosphate fertilizers MAP, DAP and TSP by titanium tetrachloride (TiCl4). The characterization of TiP2O7 was realized using spectroscopic and microscopic technics such as XRD, IR, SEM, and EDX.…”

Section: Introductionmentioning

confidence: 83%

Comparative study between the Titanium Phosphate TiP2O7 and the Phosphate Fertilizers in the catalysis of the Quinazolin-4(3H)-one derivatives synthesis

et al. 2020

View full text Add to dashboard Cite

A simple and efficient method for the synthesis of quinazolin-4(3H)-one derivatives via condensation of anthranilamide with aromatic aldehyde catalyzed by monoammonium phosphate (MAP), diammonium phosphate (DAP), and triple superphosphate (TSP), were developed. The modification of these three phosphate fertilizers using titanium tetrachloride (TiCl4) has increased their catalytic efficiency. The prepared titanium phosphate (TiP2O7) was characterized using microscopic and spectroscopic methods, namely X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), and infrared spectroscopy (IR). The TiP2O7 was applied for the first time as a heterogeneous catalyst in quinazolin-4(3H)-ones synthesis. High yields and short reaction times were observed in the determined optimal condition (solvent nature, volume, and catalyst amount). This study shows that the TiP2O7 presents an exciting catalytic activity and long-term durability compared to those of MAP, DAP, and TSP.

show abstract

Section: Introductionmentioning

confidence: 83%

Comparative study between the Titanium Phosphate TiP2O7 and the Phosphate Fertilizers in the catalysis of the Quinazolin-4(3H)-one derivatives synthesis

et al. 2020

View full text Add to dashboard Cite

show abstract

“…As a continuation of the previous studies published by our researcher's team on the design and application of phosphate catalysts in organic reactions . In order to valorize the Moroccan phosphate, one proposes a process for the preparation of Co 3 (PO 4 ) 2 , by a simple and less expensive method compared to that reported previously, that consists to modify the fertilizer phosphates mono‐ammonium phosphate MAP by Co(NO 3 ) 2 .…”

Section: Introductionmentioning

confidence: 96%

Valorization of the Modified Mono Ammonium Phosphate by Cobalt in the Synthesise of 3,4‐Dihydropyrano[c]chromene Derivatives

et al. 2019

View full text Add to dashboard Cite

This work presents a simple process for the preparation of Cobalt Orthophosphate (Co 3 (PO 4 ) 2 ), by modifying phosphate fertilizer mono-ammonium phosphate (MAP) by cobalt nitrate (Co(NO 3 ) 2 ). Co 3 (PO 4 ) 2 has been characterised using microscopic and spectroscopic methods namely X-ray diffraction (XRD), infrared spectroscopy (IR) and scanning electron microscopy (SEM). It is the first time that Co 3 (PO 4 ) 2 is used as a heterogeneous catalyst in the condensation between an aryl aldehyde, 4-hydroxycoumarin and malononitrile. The results show that Co 3 (PO 4 ) 2 is an effective catalyst for one-pot synthesis of 3,4-dihydropyrano [3, 2-c] chromene. The optimisation of each reaction parameter allows achieving excellent results in terms of time and yield. The application of Co 3 (PO 4 ) 2 as catalyst in the 3, 4-dihydropyrano [3, 2-c] chromene derivatives synthesis offers certain advantages such as shorter reaction time, simple treatment, furthermore, the catalyst possesses a great capacity for reutilization and therefore its application contributes to the development of green chemistry.[a] A.

show abstract

“…7 The aluminized polyborate catalyst was used in our previous work for the solvent-free green synthesis of various heterocyclic molecules. [8][9][10] In literature several methodologies are been reported for the synthesis of acridinediones among them some are β-CD-mono-SO3H, 11 CdS thin film, 12 MNPs-N-propyl-benzoguanamine-SO3H, 13 AFGONs, 14 GO/CR-Fe3O4, 15 Iron-4 A molecular sieves, 16 MCM-41-Pr-THEIC, 17 Pd/AlO(OH), 18 urease, 19 Fe3O4@SiO2@Ni-Zn-Fe LDH, 20 nano-Fe3O4@SiO2-HBP-FeCl3, 21 citric acid, 22 TEMPO/CuCl2, 23 N-butyl pyridinium heptachlorodialuminate, 24 L-proline, 25 microwave irradiation, 26 Na + -MMT-[bip]-NH2 + HSO4 -, 27 MSrGONCs, 28 phosphate fertilizers, 29 ChCl:urea deep eutectic solvent, 30 Fe3O4@SiO2-Pr-Sulfurol-SO3H MNPs 31 and ultrasound-assisted 32 reaction.…”

Section: Introductionmentioning

confidence: 99%

Aluminized polyborate catalyzed efficient solvent-free synthesis of 1,8-dioxo-decahydroacridines via hantzsch condensation

Aute,

Parhad,

Vikhe

et al. 2024

10.5267/j.ccl

View full text Add to dashboard Cite

In this work we report, aluminized polyborate catalyzed facile and efficient one-pot four component Hantzsch synthesis of 1,8-dioxo-decahydroacridines using substituted aromatic aldehydes (1 mmol), dimedone (2 mmol) and ammonium acetate (1.5 mmol) at 95-100oC under solvent-free condition. The prominent advantages of this methodology are good product yields (85-95%), eco-friendliness, mild reaction conditions and use of inexpensive catalyst. The structures of the targeted molecules were examined by FT-IR, 1H-NMR and mass spectral techniques.

show abstract

Synthesis of 9-Arylhexahydroacridine-1,8-diones Using Phosphate Fertilizers as Heterogeneous Catalysts

Cited by 16 publications

References 39 publications

Comparative study between the Titanium Phosphate TiP2O7 and the Phosphate Fertilizers in the catalysis of the Quinazolin-4(3H)-one derivatives synthesis

Comparative study between the Titanium Phosphate TiP2O7 and the Phosphate Fertilizers in the catalysis of the Quinazolin-4(3H)-one derivatives synthesis

Valorization of the Modified Mono Ammonium Phosphate by Cobalt in the Synthesise of 3,4‐Dihydropyrano[c]chromene Derivatives

Aluminized polyborate catalyzed efficient solvent-free synthesis of 1,8-dioxo-decahydroacridines via hantzsch condensation

Contact Info

Product

Resources

About