Abstract:To achieve the N-phenyl tetrahydroindazoles, t(3)-aryl-r(2),c(4)-bis(isopropoxycarbonyl)-c(5)-hydroxy-t(5)-methylcyclohexanones were treated with phenylhydrazine. Characterizations reveal the resultant products are respective N-phenyl dihydroindazoles. The reaction has been taken place in regioselctive manner. Plausible mechanism was proposed for the regioselective formation of dihydroindazoles with the phenyl substituent at N(2) position. Dehydration of hydroxyl group at C-6 position results double bond forma… Show more
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