Synthesis of 2‐exo‐Acryloyloxy‐N‐(1‐adamantyl)bornane‐10‐sulfonamide Diastereomers as Chiral Scaffolds.

Abstract

Diastereoselective syntheses O 0031Synthesis of 2-exo-Acryloyloxy-N-(1-adamantyl)bornane-10-sulfonamide Diastereomers as Chiral Scaffolds. -The sterically demanding title compound (I) is prepared and tested as chiral scaffold for the Baylis-Hillman reaction to give (III). For all 5 aldehydes tested yields are high, but only for (IIb) a high stereoselectivity is observed. -(DUGGAN, A. R.; KAYE*, P. T.; J. Chem. Res. 2007, 3, 148-151; Dep. Chem., Rhodes Univ., Grahamstown 6140, S. Afr.; Eng.) -M. Bohle

Lost in transition? Sexuality and justice in post-conflict Northern Ireland

“…32 Suggestions of the absence of sectarianism as a determining, dividing or denigrating force within the LGB&T community suggests that spaces were -and still may be -created outside of this paradigm. 33 The exclusion of this aspect of identity harmony and collective organising is also largely overlooked in mainstream scholarship pertaining to Northern Ireland's Troubles, illustrating the marginalised position occupied by LGB&T identities within this historical framework. It is through interrogating such processes of 'structural exclusion' which in turn feed into 'cultural imagining' of subordinated and minority groups which Perry suggests is vital in order to recognise the infrastructures facilitating the systemic violence faced by these groups.…”