Synthesis of 1,3-Dioxacycloalkyl-Containing Azoxybenzenes

Spesivaya, E. S.; Lupanova, Ida A.; Konshina, Dzh. N.; Коншин, В. В.

doi:10.1134/s1070363222080023

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Selected Applications Of 1‐alkynylsilanes1

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2024

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“…As mentioned earlier, under standard conditions, the sp C−Si bond remains untouched. However, by modifying the conditions, we can obtain a variant called the sila‐Sonogashira reaction [227] . Another interesting example was reported by Malinowski and co‐workers in 2022 (Figure 57).…”

Section: Selected Applications Of 1‐alkynylsilanesmentioning

confidence: 92%

Synthesis of Alkynylsilanes: A Review of the State of the Art

Kuciński

2024

Adv Synth Catal

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This contribution offers a comprehensive overview of methods for forging sp C–Si bonds. Over time, alkynylsilanes (silylacetylenes), once considered mere byproducts of hydrosilylation processes, have become essential building blocks in organic synthesis. This literature review traces the evolution of their synthesis, from traditional methodologies relying on organolithium and organomagnesium compounds to more advanced cross‐coupling reactions involving hydro‐ and carbosilanes. Focused primarily on the past 25 years (2000‐2024), it also extensively references significant historical breakthroughs. By analyzing synthetic methodologies, the review not only offers a comprehensive survey of the current state of knowledge but also identifies areas for improvement. Furthermore, to emphasize the importance of 1‐alkynylsilanes (1‐silyl‐1‐alkynes), selected applications of these compounds are highlighted, confirming their significant potential in organic synthesis.

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Section: Selected Applications Of 1‐alkynylsilanesmentioning

confidence: 92%

Synthesis of Alkynylsilanes: A Review of the State of the Art

Kuciński

2024

Adv Synth Catal

View full text Add to dashboard Cite

show abstract

Synthesis of 1,3-Dioxacycloalkyl-Containing Azoxybenzenes

Cited by 1 publication

References 20 publications

Synthesis of Alkynylsilanes: A Review of the State of the Art

Synthesis of Alkynylsilanes: A Review of the State of the Art

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