“…Besides, silica coating techniques have been also used to prepared soft magnetic composites [14][15][16]. SiO 2 is commonly used as surfaced shell of magnetic core-shell nanoparticles because of its good chemical inertness, high suspension stability and non-toxicity [16][17][18][19][20][21][22][23][24]. In recent years, silica-coated iron particles have also been investigated as a novel kind of SMCs by many researchers [9,14,15], while few studies have been carried out for the FeSiAl-based soft magnetic materials.…”
Section: And Aln Have Been Investigated In Smcsmentioning
“…Besides, silica coating techniques have been also used to prepared soft magnetic composites [14][15][16]. SiO 2 is commonly used as surfaced shell of magnetic core-shell nanoparticles because of its good chemical inertness, high suspension stability and non-toxicity [16][17][18][19][20][21][22][23][24]. In recent years, silica-coated iron particles have also been investigated as a novel kind of SMCs by many researchers [9,14,15], while few studies have been carried out for the FeSiAl-based soft magnetic materials.…”
Section: And Aln Have Been Investigated In Smcsmentioning
“…The Fe@SiO 2 /polymer nanocomposites have higher magnetodielectric properties [dielectric permittivity ( ɛ ), dielectric loss (tan δ ), magnetic permeability ( μ )] at radio frequencies (1 MHz–1 GHz), renders it as a good candidate for dielectric applications [7]. The Fe@SiO 2 nanoparticles exhibit superferromagnetism properties, renders it as a good candidate for microelectronics applications [5, 8]. In addition, nanoscale zero‐valent iron (NZVI) nanocomposites are well‐known for their application in environmental fields due to their small particle size, large surface area and high in situ reactivity.…”
Section: Introductionmentioning
confidence: 99%
“…The most widely reported method is to coat the nanoparticles with a protective shell to form core-shell nanocomposites. The materials of protective shell include silica [4][5][6][7][8][9][10], carbon [11,12], titanium oxide [13,14], polymers [15] etc. The core-shell nanocomposites have many potential applications, such as drug delivery, bioimaging, catalytic, electronic, microwave absorbents and environmental remediation [16][17][18][19][20][21].…”
The monodisperse Fe@SiO 2 core-shell nanocapsules were synthesised via hydrothermal reaction followed with heat treatment. Nanostructures were characterised by X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The magnetic properties of Fe@SiO 2 nanocapsules were evaluated with magnetic property measurement system. The results show that Fe@SiO 2 core-shell nanocapsules are highly monodispersed. The silica thickness of Fe@SiO 2 nanocapsules increased from 10-20 to 25-35 nm with increasing tetraethyl orthosilicate (TEOS) amount. In the Fe@SiO 2 nanocapsules prepared with 900 μl TEOS, as the reaction temperature increases, the mean particle size of Fe@SiO 2 nanocapsules increases from 328 to 546 nm. It is remarkable that the saturation magnetisation of Fe@SiO 2 nanocapsules decreases with increasing silica thickness. However, the coercivity of nanocapsules has less influence with the variation of silica thickness and particles' length.
“…[2], while as inorganic insulation mostly the FePO 4 , MgO and SiO 2 are applied, e.g. [3][4][5][6]. This paper deals with the eect of the shape of iron particles on continuity and distribution of insulating layer in the Fe/SiO 2 composites prepared by VPI with shellac and/or SL450 thermoset, as well as by mixing the Fe/SiO 2 powder with shellac.…”
Fe/SiO2 powder composite materials based on irregularly and/or spherically shaped iron powder particles with an addition of SiO2 nanopowder were prepared in two ways, (i) by mixing the Fe/SiO2 powder with 1.0 wt.% of Shellac dissolved in ethanol and (ii) by vacuum/pressure impregnation of low-temperature sintered Fe/SiO2 components with shellac dissolved in ethanol and with thermoplast SL450. SiO2 was implemented either as nanopowder or by sol-gel coating. Vacuum/pressure impregnation (VPI) of pre-sintered samples was performed in a steel container. The inuence of iron particle shape and processing conditions on the electro-insulating layer was microscopically evaluated and correlated with the values of the electrical resistivity and coercivity. It has been found that the continuity, distribution and thickness of insulating phase is strongly controlled by the shape of iron particles. Using the VPI procedure, the irregular surface of iron particles may cause discontinuities of insulating layer, while the spherical iron particles are well covered with continuous evenly distributed insulating layer.
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