Synthesis, growth, structural, optical and thermal properties of a new semiorganic nonlinear optical guanidinium perchlorate single crystal

(2-Azoniaethyl)guanidinium dichloride – A promising phase-matchable NLO material employing a simple hydrogen bond acceptor in its structure

“…This concept was successfully employed in the preparation of non-centrosymmetric crystalline materials containing hydrogen-anions derived from inorganic acids that act as H-bond donors [5][6][7]. Besides, there has been reported a considerable number of analogous materials containing fully deprotonated inorganic anions, which can only act as H-bond acceptors [7][8][9]. Building upon this strategy, we have decided to evaluate the structural role of the simplest common inorganic Hbond acceptor -the chloride anion -in a family of selected guanidine-based materials, whose crystal packing will be thus mainly influenced by the nature of the used cation.…”

Synthesis, growth and characterization of l-asparagine cadmium bromide: A novel semiorganic nonlinear optical single crystal

“…5. From the TGA curve there is no weight loss observed below 105.55 • C was due to absence of crystallization of water in the molecular structure [19]. In the DTA curve first endothermic peak observed at 121 • C was due to physically absorbed water is confirmed by sharp peak in DSC trace as shown in Fig.…”

Growth and Characterization of Non-Linear Optical Single Crystal Guanidinium triscadmium Sulphate Octahydrate

“…The work hardening coefficient (n) was calculated from Mayer′s relation (P) = Kd n connecting load P and average diagonal length d of indentation, K is the material constant. The work hardening coefficient (n) of grown crystal was determined from the plot of log P against log d for GuCdS crystal and is shown [25] Present study in Fig. 12.…”