“…7 F J (J = 0, 1, 2) electronic transitions of Eu 3+ , respectively. [29][30][31] Besides, an emission band peaking at 422 nm can be better identified upon excitation at k ex = 360 nm which can be ascribed to the existence of Eu 2+ . The excitation peaks at 362, 380 and 394 nm (k em = 616 nm) are assigned to the 7 F 0 ?…”
Section: Resultsmentioning
confidence: 95%
“…The excitation and emission spectra of Ca 2.99 B 2 O 6 :0.01Eu phosphor are shown in Figure A. The emission bands centered at around 587, 597, and 616 nm arise from the 5 D 0 → 7 F J (J = 0, 1, 2) electronic transitions of Eu 3+ , respectively . Besides, an emission band peaking at 422 nm can be better identified upon excitation at λ ex = 360 nm which can be ascribed to the existence of Eu 2+ .…”
The Dy‐ and Eu‐activated Ca3B2O6 phosphors were synthesized by a high‐temperature solid‐state reaction technique and their structural and luminescent properties were investigated. The phosphors are characterized by X‐ray diffraction, photoluminescence spectra, and Commission International de I'Eclairage (CIE) chromaticity coordinates. It is found that the charge compensator Na+ plays an important role in modifying the emission spectral profiles of Dy and Eu ions in the phosphors. The ratio of the emission located at the yellow wavelength portion to that located at the blue wavelength region of the Dy3+ ions can be apparently tuned by changing the Na+ content. The luminescence intensity of the phosphors can be enhanced with introducing Na+ ions as well. The emission colors of Dy/Eu codoped phosphors change from blue to white and successfully acquire the superior white light emission (x = 0.330, y = 0.329) by appropriately tuning the Na+/Dy3+ content and the excitation wavelength. The energy transfer process from Eu2+ to Dy3+ and Eu3+ occurs in the Dy/Eu codoped phosphors, providing a further approach to modify the emission spectral profile of the examined phosphors. The phosphors presented here have promising applications in the fields of light‐emitting diodes.
“…7 F J (J = 0, 1, 2) electronic transitions of Eu 3+ , respectively. [29][30][31] Besides, an emission band peaking at 422 nm can be better identified upon excitation at k ex = 360 nm which can be ascribed to the existence of Eu 2+ . The excitation peaks at 362, 380 and 394 nm (k em = 616 nm) are assigned to the 7 F 0 ?…”
Section: Resultsmentioning
confidence: 95%
“…The excitation and emission spectra of Ca 2.99 B 2 O 6 :0.01Eu phosphor are shown in Figure A. The emission bands centered at around 587, 597, and 616 nm arise from the 5 D 0 → 7 F J (J = 0, 1, 2) electronic transitions of Eu 3+ , respectively . Besides, an emission band peaking at 422 nm can be better identified upon excitation at λ ex = 360 nm which can be ascribed to the existence of Eu 2+ .…”
The Dy‐ and Eu‐activated Ca3B2O6 phosphors were synthesized by a high‐temperature solid‐state reaction technique and their structural and luminescent properties were investigated. The phosphors are characterized by X‐ray diffraction, photoluminescence spectra, and Commission International de I'Eclairage (CIE) chromaticity coordinates. It is found that the charge compensator Na+ plays an important role in modifying the emission spectral profiles of Dy and Eu ions in the phosphors. The ratio of the emission located at the yellow wavelength portion to that located at the blue wavelength region of the Dy3+ ions can be apparently tuned by changing the Na+ content. The luminescence intensity of the phosphors can be enhanced with introducing Na+ ions as well. The emission colors of Dy/Eu codoped phosphors change from blue to white and successfully acquire the superior white light emission (x = 0.330, y = 0.329) by appropriately tuning the Na+/Dy3+ content and the excitation wavelength. The energy transfer process from Eu2+ to Dy3+ and Eu3+ occurs in the Dy/Eu codoped phosphors, providing a further approach to modify the emission spectral profile of the examined phosphors. The phosphors presented here have promising applications in the fields of light‐emitting diodes.
“…15 It is well known that RE ions doped luminescent materials are plentiful luminescent resources due to their abundant energy levels. 16,17 Eu 3+ ion is a red activator originating from 5 D 0 -7 F J (J ¼ 0, 1, 2, 3, 4) transitions under UV light excitation. 17,18 Bi 3+ ion is another kind of activator, whose luminescence is attributed to the transition from 6s 2 to 6s6p with broad absorption band in UV region.…”
Section: Introductionmentioning
confidence: 99%
“…16,17 Eu 3+ ion is a red activator originating from 5 D 0 -7 F J (J ¼ 0, 1, 2, 3, 4) transitions under UV light excitation. 17,18 Bi 3+ ion is another kind of activator, whose luminescence is attributed to the transition from 6s 2 to 6s6p with broad absorption band in UV region. 19,20 Bi 3+ ion can emit various wavelength including ultraviolet, blue, green, yellow and even red bands in different hosts.…”
“…Luminescent materials, especially lanthanide-doped materials, have attracted extensive synthetic interest due to their remarkable luminescence properties, such as various emission colours, high photochemical stability, low toxicity, narrow emission peaks and large anti-Stokes shifts [1–8]. These advantages lead to their excellent performance in versatile applications such as lighting, information display technologies, solar cells, biological labelling and biomedical imaging technology [9–13].…”
Hollow lanthanide-doped compounds are some of the most popular materials for high-performance luminescent devices. However, it is challenging to find an approach that can fabricate large-scale and well-crystallized lanthanide-doped hollow structures and that is facile, efficient and of low cost. In this study, YBO3: Eu3+/Tb3+ hollow microspheres were fabricated by using a novel multi-step transformation synthetic route for the first time with polystyrene spheres as the template, followed by the combination of a facile homogeneous precipitation method, an ion-exchange process and a calcination process. The results show that the as-obtained YBO3: Eu3+/Tb3+ hollow spheres have a uniform morphology with an average diameter of 1.65 µm and shell thickness of about 160 nm. When used as luminescent materials, the emission colours of YBO3: Eu3+/Tb3+ samples can be tuned from red, through orange, yellow and green-yellow, to green by simply adjusting the relative doping concentrations of the activator ions under the excitation of ultraviolet light, which might have potential applications in fields such as light display systems and optoelectronic devices.
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