Synthesis, crystal structures, thermal decomposition mechanism and thermal properties of mononuclear ternry lanthanide complex with 2,4-dichlorobenzoic acid and 2,2&amp;prime;:6&amp;prime;,2&amp;Prime;-terpyridine

A novel manganese complex, C 16 H 26 MnN 4 O 12 , was synthesized by the reaction of nicotinoyl-glycine and NaOH in an ethanol/water solution and structurally characterized by elemental analysis, UV-vis spectrum, IR spectrum and single-crystal X-ray diffraction analysis. The crystal of the complex belongs to the triclinic space group P 1 with a = 7.8192(16) Å, b = 8.8800(18) Å, c = 9.0142(18) Å, α = 83.14(3) • , β = 65.27(3) • , γ = 81.67(3) • , V = 516.3(2) Å 3 , Z = 1, Dx = 1.542 mg·m −3 , µ = 0.66 mm −1 , F(000) = 271, and final R 1 = 0.0381, ωR 2 = 0.0964. The nicotinoyl-glycine ligand acts as a bridging ligand to connect the manganese ions by the hydrogen interactions; thus, the complex expands into a 3D supramolecular net structure.

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Synthesis, crystal structures, thermal decomposition mechanism and thermal properties of mononuclear ternry lanthanide complex with 2,4-dichlorobenzoic acid and 2,2′:6′,2″-terpyridine

Abstract: , crystal structures, thermal decomposition mechanism and thermal properties of mononuclear ternry lanthanide complex with 2,4-dichlorobenzoic acid and 2,2′ ′:6′ ′,2″ ″-terpyridine 王叶, 靳成伟, 任宁 and 张建军

Cited by 2 publications

References 14 publications

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Syntheses, structures and photophysical properties of Ni/Co Ln coordination polymers

Synthesis, Crystal Structure of a Novel Mn Complex with Nicotinoyl-Glycine

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