“…The dicyanamido complexes display a wide range of coordination modes with divalent metal ions ranging from simple coordination mode to the terminal or central amide group (µ 1 or µ 3 ) [13,14,20,41] to complex modes including both of them. These modes, which are illustrated in Scheme 1 and have been previously summarized [10,14], include µ2 bonding: µ 1,5 (end-to-end), µ 1,1 (end-on), and µ 1,3 [9][10][11][12][13][14][17][18][19][20][21]23,41]; µ3 bonding: µ 1,1,5 and µ 1,1,3 [14,[18][19][20]24,25,[42][43][44][45][46][47][48][49]; µ4 bonding: µ 1,1,5,5 and µ 1,1,3,5 ; and µ5 bonding: µ 1,1,3,5,5 [14,18,24,25,[45][46][47][48][49]. The majority of bridged-dicyanamido-metal(II) complexes exhibit weak antiferromagnetic coupling [10][11][12][13]…”