Synthesis, crystal structures and multinuclear NMR spectroscopy of copper(I) complexes with benzophenone thiosemicarbazone

Synthesis and structural characterization of binuclear palladium(II) complexes of salicylaldimine dithiosemicarbazones

“…The IR spectra of the palladium complexes 7-12 show a band of medium to strong intensity within 1599-1589 cm , indicative of the presence of coordinated PPh 3 in the complexes [35][36][37]. Bands involving the C@S functional group are often difficult to assign.…”

Synthesis, characterization, and antibacterial activities of copper(I) bromide complexes of thioureas: X-ray structure of [Cu(Metu)4]Br

“…The interaction of thiourea and substituted thioureas with metal ions has been the subject of several recent investigations because of their variable binding modes and because of the relevance of their binding sites to those in living systems [1][2][3][4][5][6][7][8][9][10][11][12]. A large number of spectral and structural studies on copper(I) complexes containing thioamides reveal that these ligands are coordinated via the sulfur atom either in a triplanar or in tetrahedral environment .…”

Ruthenium(II) Complexes of Thiosemicarbazones: The First Water‐Soluble Complex with pH‐Dependent Antiproliferative Activity

“…The thiosemicarbazone can act as a monodentate ligand that binds to the metal ion through the sulfur atom [1] or as a bidentate ligand that coordinates to the metal ion through the sulfur atom and one of the nitrogen atoms of the hydrazine moiety to form a four-or a five-membered metallacycle. [2,3] The coordination capacity of thiosemicarbazones can be increased by using for their preparation aldehydes or ketones containing additional functional group(s) in position(s) suitable for chelation.…”