“…This then leads to multimetallic complexes where all the metal ions are in the same coordination environment. For bimetallic species, commonly‐observed coordination motifs involving dithiolene ligands include [M 2 (dithiolene) 4 ] (M = Mn,, Fe,, Co,, , Ni,, ), [M 2 (dithiolene) 5 ] (M = Mo, Rh, Re), and [M 2 (Cp) 2 (dithiolene) 2 ] (Cp = cyclopentadienyl, M = V, Cr, Fe, Co, Mo, Rh) . In such complexes, the coordination environment around one metal center is almost always the same as that around the other metal center, and this is especially true when the metals in question are drawn from the first row of the d‐block.…”