Synthesis, crystal structure, thermal stability and biological study of bis{(2-methoxy-6-[(E)-(propylimino)methyl]phenolato}nickel(II) complex

Sindhu, S.; Arockiasamy, S.

doi:10.1016/j.heliyon.2024.e24108

Heliyon

2024

DOI: 10.1016/j.heliyon.2024.e24108

|View full text |Cite

Synthesis, crystal structure, thermal stability and biological study of bis{(2-methoxy-6-[(E)-(propylimino)methyl]phenolato}nickel(II) complex

S. Sindhu,

S. Arockiasamy

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Preprint1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

References 59 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Synthesis, crystal structure, and Hirshfeld surface analysis of (E)-N, N´-ethylene-1,2- diamino-bis (N, N-dimethylbut-2-enamide)

Ganesan,

Ayyappan,

Arockiasamy

2024

Preprint

View full text Add to dashboard Cite

The compound, (E)-N, N´-ethylene-1,2-diamino-bis(N, N’-dimethylbut-2-enamide) was synthesized by a reaction between N, N´-dimethylacetoacetamide and ethylenediamine in a methanolic medium. The Schiff base compound was characterized by infrared (IR) spectroscopy, mass spectrometry (MS), thermogravimetry (TG), and single-crystal X-ray diffraction (XRD). The compound was crystallised in a triclinic crystal system with a space group of P-1. The amine functional group (-C = N-) was confirmed by the band at 1592 cm− 1 in its IR spectrum. The compound is thermally stable from 40–203 oC losing only 1.4% of its weight. The thermogram (TG) indicated the absence of any water of hydration or lattice water. The compound exhibits keto-enol tautomerism with a zwitterionic structure. The major contributors to the Hirshfeld surface (HS) contacts are H—H (71%), O—H (11.7%), and C—H (12.2%). The crystal parameters are, a = 6.3623(4) Å, b = 6.5585(4) (8) Å, c = 10.8135(7) Å, Z = 4, R1 = 0.0610, wR2 = 0.1447. α = 98.16 (4)o, β = 95.86(4)o, γ = 117.63(4)o.

show abstract

Synthesis, crystal structure, and Hirshfeld surface analysis of (E)-N, N´-ethylene-1,2- diamino-bis (N, N-dimethylbut-2-enamide)

Ganesan,

Ayyappan,

Arockiasamy

2024

Preprint

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

hi@scite.ai

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Synthesis, crystal structure, thermal stability and biological study of bis{(2-methoxy-6-[(E)-(propylimino)methyl]phenolato}nickel(II) complex

Cited by 1 publication

References 59 publications

Synthesis, crystal structure, and Hirshfeld surface analysis of (E)-N, N´-ethylene-1,2- diamino-bis (N, N-dimethylbut-2-enamide)

Synthesis, crystal structure, and Hirshfeld surface analysis of (E)-N, N´-ethylene-1,2- diamino-bis (N, N-dimethylbut-2-enamide)

Contact Info

Product

Resources

About