Synthesis, crystal structure, Hirshfeld surface analysis and dielectric properties of a new centrosymmetric hybrid compound (C4H12NO3)CdCl3·H2O

Dadi, Ahlem; Jellali, Aycha; Messoudi, Nouha; Khirouni, K.; Mezzadri, Francesco; Loukil, M.

doi:10.1016/j.poly.2019.05.036

Cited by 5 publications

(1 citation statement)

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“…The distance between successive metal cadmium is 3.846 (0) Å and the Cd-Cd-Cd angle is 164.58(1) • , showing that the polymeric chains are approximately linear. These values are consistent with those found for other comparable halogenocadmate systems [47][48][49][50].…”

Section: 21crystal Structure Of [(C7h10no2)cdcl3]n(i)supporting

confidence: 92%

The Coordination Behavior of Two New Complexes, [(C7H10NO2)CdCl3]n(I) and [(C7H9NO2)CuCl2] (II), Based on 2,6-Dimethanolpyridine; Elaboration of the Structure and Hirshfeld Surface, Optical, Spectroscopic and Thermal Analysis

et al. 2022

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Two novel complexes, [(C7H10NO2)CdCl3]n(I) and [(C7H9NO2)CuCl2],havebeen synthesized and characterized. Single crystal X-ray diffraction revealed that in compound (I), 2,6-dimethanol pyridinium acts as a monodentate ligand through the O atom of the hydroxyl group. Contrarily, the 2,6-dimethanol pyridine ligand interacts tridentately with the Cu(II) ion via the nitrogen atoms and the two oxygen (O, O’) atoms of the two hydroxyl groups. The structure’s intermolecular interactions were studied using contact enrichment ratios and Hirshfeld surfaces. Following metal coordination, numerous hydrogen connections between entities and parallel displacement stacking interactions between pyridine rings dictate the crystal packing of both compounds. The aromatic cycles generate layers in the crystal for both substances. Powder XRD measurements confirmed the crystalline sample phase purity. SEM confirmed the surface homogeneity, whereas EDX semi-quantitative analysis corroborated the composition. IR spectroscopy identified vibrational absorption bands, while optical UV-visible absorption spectroscopy investigated optical properties. The thermal stability of the two materials was tested using TG-DTA.

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Section: 21crystal Structure Of [(C7h10no2)cdcl3]n(i)supporting

confidence: 92%